What will be the emf of the cell in which the following reaction takes place? Given Ecell° = 1.05 V

Ni(s)+2Ag+(0.002 M) Ni2+(0.160 M) + 2Ag(s)

1. 0.80 V

2. 0.91 V

3. 0.45 V

4. 0.36 V

Subtopic:  Nernst Equation |
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The cell in which the following reactions occurs:

2Fe3+(aq)+2I-(aq)2Fe2+(aq)+I2(s) has  \(E_{cell}^{o}\) = 0.236 V at 298 K.

The equilibrium constant of the cell reaction is : 

1. 9.57 × 107
2. 8.43 × 106
3. 3.68 × 10-7
4. 1.74 × 105

Subtopic:  Relation between Emf, G, Kc & pH |
 63%
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The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol−1.

What is the dissociation constant of methanoic acid? Given λ°(H+)= 349.6 S cm2 mol−1 and λ°(HCOO) = 54.6 S cm2 mol-1

1. 2.43 × 104 mol L-1
2. 1.15 × 10-5 mol L-1
3. 3.67 × 10-4 mol L-1
4. 2.44 × 10-6 mol L-1

Subtopic:  Conductance & Conductivity |
 61%
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Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)

EMg2+/Mgo=-2.36 V; ECu2+/Cuo=0.34V

The value of Ecell  for the above reaction is -

1. 3.46 V  2. 3.15 V
3. 2.67 V 4. 1.24 V
Subtopic:  Nernst Equation |
 86%
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The cell that will measure the standard electrode potential of a copper electrode is:

1. Pt(s) | H2(g, \(1 \over 10\) bar) | H+(aq, 1M) || Cu2+(aq, 1M) | Cu
2. Pt(s) | H2(g, 1 bar) | H+(aq, 1M) || Cu2+ (aq, 2M) | Cu
3. Pt(s) | H2(g, 1 bar) | H+(aq, 1M)|| Cu2+ (aq, 1M) | Cu
4. Pt(s) | H2(g, \(1 \over 10\) bar) | H+(aq, \(1 \over 10\)M) || Cu2+(aq, 1M) | Cu

Subtopic:  Electrolytic & Electrochemical Cell |
 77%
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The electrode potential for Mg electrode varies according to the equation

\(E_{Mg^{2+}/Mg}\ = \ E_{Mg^{2+}/Mg}^{o} \ - \ \frac{0.059}{2}log\frac{1}{[Mg^{2+}]}\) 

The graph of EMg2+ / Mg vs log [Mg2+] among the following is:

1.    2.  
3.    4.  
Subtopic:  Nernst Equation |
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The correct statement among the following options is: 

1. Ecell and ∆rG of cell reaction are both extensive properties.
2. Ecell and ∆rG of cell reaction are both intensive properties.
3. Ecell is an intensive property while ∆rG of cell reaction is an extensive property.
4. Ecell is an extensive property while ∆rG of cell reaction is an intensive property.

Subtopic:  Electrode & Electrode Potential |
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The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called:
1. Cell potential.
2. Cell emf.
3. Potential difference.
4. Cell voltage.

Subtopic:  Electrode & Electrode Potential |
 64%
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The incorrect statement about an inert electrode in a cell is:

1. It does not participate in the cell reaction.
2. It provides a surface either for oxidation or for the reduction reaction.
3. It provides a surface for the conduction of electrons.
4. It provides a surface for redox reaction.

Subtopic:  Electrode & Electrode Potential |
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An electrochemical cell can behave like an electrolytic cell when -

1. Ecell = 0

2. Ecell > Eext

3. Eext > Ecell

4. Ecell = Eext

Subtopic:  Electrolytic & Electrochemical Cell |
 66%
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