Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is:
1. Hexane > Ethyne > Benzene
2. Benzene > Hexane > Ethyne
3. Ethyne > Benzene > Hexane
4. Benzene > Ethyne > Hexene
Incorrect statement towards reactivity of benzene is:
| 1. | It undergoes electrophilic substitution reactions very easily. |
| 2. | Nucleophiles are attracted by a benzene ring. |
| 3. | Benzene is a planar molecule. |
| 4. | It has 12 sigma bonds. |
The reagent used in the above conversion is:
1. Cr2O3
2. Alc. KOH
3. Red hot Fe
4. NaNH2/liq.NH3
Out of the above alkenes, the ones that can give 2-methyl butane on hydrogenation are:
| 1. | a, b | 2. | b, c |
| 3. | a, c | 4. | a, b, c |
The correct order of decreasing reactivity of the following compounds:
Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene
with an electrophile (E+) is :
| 1. | Chlorobenzene > p–Nitrochlorobenzene > 2,4-Dinitrochlorobenzene |
| 2. | p – Nitro chlorobenzene > 2, 4-Dinitrochlorobenzene > Chlorobenzene |
| 3. | Chlorobenzene > 2, 4-Dinitrochlorobenzene > p-Nitrochlorobenzene |
| 4. | 2, 4-Dinitrochlorobenzene > Chlorobenzene > p-Nitrochlorobenzene |
The products of ozonolysis of 1,2-dimethyl benzene (o-xylene) are:
1. Methylglyoxal, 1, 2-dimethylglyoxal, and glyoxal
2. Methylglyoxal, 1, 3-dimethylglyoxal, and glyoxal
3. Methylglyoxal, 1, 4-dimethylglyoxal, and glyoxal
4. Methylglyoxal, 1, 5-dimethylglyoxal, and glyoxal
Match the hydrocarbons in Column I with the boiling points given in Column II.
| A. n-Pentane | 1. 282.5 K |
| B. Isopentane | 2. 309 K |
| C. Neopentane | 3. 301 K |
Codes
| Options: | A | B | C |
| 1. | 2 | 3 | 1 |
| 2. | 1 | 2 | 3 |
| 3. | 2 | 1 | 3 |
| 4. | 3 | 2 | 1 |
Match the reactions given in Column-I with the type of reaction given in Column-II and mark the appropriate option:
| Column-I | Column-II | ||
| A. | CH2=CH2 + H2O \(\xrightarrow[]{H^{+}}\) CH3CH2OH |
1. | Hydrogenation |
| B. | CH2=CH2 + H2 \(\xrightarrow[]{Pd}\) CH3-CH3 |
2. | Halogenation |
| C. | CH2=CH2 + Cl2 → Cl-CH2-CH2-Cl |
3. | Polymerisation |
| D. | 3CH≡CH \(\xrightarrow[heat]{Cu \ tube}\) C6H6 |
4. | Hydration |
| 5. | Condensation | ||
Codes:
| Options: | A | B | C | D |
| 1. | 2 | 3 | 4 | 1 |
| 2. | 1 | 2 | 3 | 5 |
| 3. | 5 | 4 | 3 | 2 |
| 4. | 4 | 1 | 2 | 3 |
| Assertion (A): | Toluene on Friedel Crafts methylation gives o- and p- xylene. |
| Reason (R): | -group bonded to benzene ring increases electron density at o- and p- position. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True and (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| Assertion (A): | Nitration of benzene with nitric acid requires the use of concentrated sulphuric acid. |
| Reason (R): | The mixture of concentrated sulphuric acid and concentrated nitric acid produces the electrophile, NO2+ . |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
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