The set of oxides of nitrogen that are paramagnetic in nature is:
1. NO, N2O
2. N2O3, NO
3. NO, NO2
4. N2O, NO2
Which of the compounds given below will exhibit a linear structure?
1. NO2
2. HOCl
3. O3
4. N2O
Match the compounds of Xe in Column I with the molecular structure in Column II.
Column-I | Column-II | ||
(a) | XeF2 | (i) | Square planar |
(b) | XeF4 | (ii) | Linear |
(c) | XeO3 | (iii) | Square pyramidal |
(d) | XeOF4 | (iv) | Pyramidal |
(a) | (b) | (c) | (d) | |
1. | (ii) | (i) | (iii) | (iv) |
2. | (ii) | (iv) | (iii) | (i) |
3. | (ii) | (iii) | (i) | (iv) |
4. | (ii) | (i) | (iv) | (iii) |
Match the coordination number and type of hybridization with the distribution of hybrid orbitals in space based on Valence bond theory.
Coordination number and type of hybridisation | Distribution of hybrid orbitals in space | ||
(a) | 4, sp3 | (i) | Trigonal bipyramidal |
(b) | 4, dsp2 | (ii) | Octahedral |
(c) | 5, sp3d | (iii) | Tetrahedral |
(d) | 6, d2sp3 | (iv) | Square planar |
(a) | (b) | (c) | (d) | |
1. | (ii) | (iii) | (iv) | (i) |
2. | (iii) | (iv) | (i) | (ii) |
3. | (iv) | (i) | (ii) | (iii) |
4. | (iii) | (i) | (iv) | (ii) |
List I Molecule |
List II Shape or geometry of the molecule |
|
a. | PCl5 | Trigonal |
b. | SF6 | Octahedral |
c. | BeCl2 | Linear |
d. | NH3 | Trigonal pyramidal |
1. | b | 2. | c |
3. | d | 4. | a |
The potential energy (y) curve for H2 formation as a function of internuclear distance (x) of the H atoms is shown below.
The bond energy of H2 is:
1. | (b – a) | 2. | \(\dfrac{\left(\right. c - a \left.\right)}{2}\) |
3. | \(\dfrac{\left(\right. b - a \left.\right)}{2}\) | 4. | (c – a) |
How many (i) sp2 hybridised carbon atoms and (ii) bonds are present in the following compound?
1. | 7, 5 | 2. | 8, 6 |
3. | 7, 6 | 4. | 8, 5 |
During change of to ion, the electron adds in which one of the following orbitals?
1.
2.
3.
4.
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them.
1. O2– < NO < C22– < He2+
2. C22– < He2+ < O2– < NO
3. He2+ < O2– < NO < C22–
4. NO < O2– < C22– < He2+
The pairs of species of oxygen and their magnetic behaviours are given below. Which of the following represents the correct description?
1. - Both paramagnetic
2. - Both diamagnetic
3. - Both paramagnetic
4. - Both paramagnetic