A compound that does not undergo SN1 reaction with OH- is:
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\(C_6H_5CH_2Br \xrightarrow[2.~H_3O^+] {1.Mg,Ether}~\mathrm X, \)
The product 'X' in the above reaction is:
1. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH} \)
2. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_3 \)
3. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{C}_6 \mathrm{H}_5 \)
4. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OCH}_2 \mathrm{C}_6 \mathrm{H}_5\)
Which of the following compounds undergoes nucleophilic substitution reaction most easily?
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| 3. | 4. |
Consider the reactions:
| (i) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5OH}{(CH_3)}_2CHCH_2OC_2H_5 + HBr}\) |
| (ii) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5O^-}{(CH_3)}_2CHCH_2OC_2H_5 + Br^-}\) |
The mechanisms of reactions (i) and (ii) are, respectively:
Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
1. Ethyl chloride
2. Isopropyl chloride
3. Benzyl chloride
4. Chlorobenzene
The –OH group of an alcohol or the carboxylic acid can be replaced by – Cl using:
| 1. | Hypochlorous acid | 2. | Chlorine |
| 3. | Hydrochloric acid | 4. | Phosphorous pentachloride |
Given below is a reaction sequence:
\(\begin{aligned} & CH_3CH_2Cl\xrightarrow{NaCN}X\xrightarrow{H_2/Ni}Y\\ &Y\xrightarrow{\text{Acetic Anhydride}}Z \end{aligned}\)
Z in the above reaction is:
1. CH3CH2CH2NHCOCH3
2. CH3CH2CH2NH2
3. CH3CH2CH2CONHCH3
4. CH3CH2CH2CONHCOCH3
The compound \(CH_3-CH_2-CH(Cl)-CH_3\) obtained by chlorination of n-butane is an example of :
1. Meso form
2. Racemic mixture
3. d-form
4. l-form
An organic compound A, having molecular formula C₄H₉Cl, reacts with sodium in dry diethyl ether to give a hydrocarbon.
This hydrocarbon on monochlorination gives only one chloro derivative.
Identify compound A.
1. t-Butyl chloride
2. sec. Butyl chloride
3. Iso butyl chloride
4. n-Butyl chloride
Find the correct sequence of the bond enthalpy of the "C-X" bond among the following:
1. CH3-F < CH3-Cl > CH3-Br > CH3-I
2. CH3-Cl > CH3-F > CH3-Br > CH3-I
3. CH3-F < CH3-Cl < CH3-Br < CH3-I
4. CH3-F > CH3-Cl > CH3-Br > CH3-I