What is the entropy change (in JK–1 mol–1) when one mole of ice is converted into water at 0 ºC? (The enthalpy change for the conversion of ice to liquid water is 6.0 KJ mol–1 at 0 ºC)
1. | 20.13 | 2. | 2.013 |
3. | 2.198 | 4. | 21.98 |
The formation of a solution from two components can be considered as:
(i) | Pure solvent → separated solvent molecules, ∆H1 |
(ii) | Pure solute → separated solute molecules, ∆H2 |
(iii) | Separated solvent and solute molecules → solution, ∆H3 |
The solution so formed will be ideal if:
1. ∆HSoln = ∆H1 + ∆H2 + ∆H3
2. ∆HSoln = ∆H1 + ∆H2 – ∆H3
3. ∆HSoln = ∆H1 – ∆H2 – ∆H3
4. ∆HSoln = ∆H3 – ∆H1 – ∆H2
The molar heat capacity of water at constant pressure, C, is 75 JK–1 mol–1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of the water is:
1. | 1.2 K | 2. | 2.4 K |
3. | 4.8 K | 4. | 6.6 K |
The thermodynamic stability of NO(g) based on the above data is:
1. Less than NO2(g)
2. More than NO2(g)
3. Equal to NO2(g)
4. Insufficient data
The entropy change in the surroundings when 1.00 mol of H2O(l) is formed under standard conditions is:
∆fHθ = –286 kJ mol–1
1. 952.5 J mol-1
2.
3.
4.
For the graph given below, it can be concluded that work done during the process shown will be-
1. | Zero | 2. | Negative |
3. | Positive | 4. | Cannot be determined |
Consider the following graph.
The work done, as per the graph above, is:
1. | Positive | 2. | Negative |
3. | Zero | 4. | Cannot be determined |
Consider the following diagram for a reaction .
The nature of the reaction is-
1. Exothermic
2. Endothermic
3. Reaction at equilibrium
4. None of the above
What is the nature of the reaction depicted in the given diagram for A→C?
1. | Exothermic | 2. | Endothermic |
3. | Reaction at equilibrium | 4. | None of these |
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference (∆Gº) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond at 298 K is:
1. 11.08
2.
3.
4. 11.08