100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torr. If the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be:
1. | 326 torr | 2. | 226 torr |
3. | 360.7 torr | 4. | 280.7 torr |
The major component of air is nitrogen with approximately 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K. if the Henry’s law constant for nitrogen at 298 K is 6.51 × 107 mm respectively, then the composition of nitrogen in air will be :
1. 12.4 × 10−5
2. 9.22 × 10−5
3. 3.54 × 10−5
4. 4.96 × 10−5
The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is:
1. | 1.02 g | 2. | 4.35 g |
3. | 2.87 g | 4. | 3.42 g |
If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-
1.
2.
3.
4. 91.28 %, 8.72 %
The type of inter molecular interactions present in
(a) | Methanol and Acetone | (i) | Van der Waal’s forces of attraction |
(b) | Acetonitrile and Acetone | (ii) | ion-dipole interaction |
(iii) | dipole-dipole interaction |
(a) | (b) | |
1. | (iii) | (ii) |
2. | (ii) | (ii) |
3. | (iii) | (iii) |
4. | (iii) | (i) |
Mole fraction of benzene in a solution where benzene constitutes 30% by mass in carbon tetrachloride (\(\text{CCl}_4\)) is
1. 0.46
2. 0.64
3. 0.91
4. 0.19
What mass of urea is needed to prepare 2.5 kg of a 0.25 m aqueous solution?
1. | 73 g | 2. | 37 g |
3. | 48 g | 4. | 24 g |
The molarity of a 20% (mass/mass) KI solution with a density of 1.202 g/mL will be:
1. 2.34 M
2. 1.45 M
3. 3.32 M
4. 0.23 M
The solubility of H2S in water at STP is 0.195 m. The value of Henry's constant is-
1. | 274 atm | 2. | 285 atm |
3. | 295 atm | 4. | 278 atm |
A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. The mass percentage of the solvent in resulting solution is:
1. 66.43 %
2. 36.54 %
3. 12.45 %
4. 33.97 %