The following metals should be arranged so that they push one another out of the salt solution in that order:
Al, Cu, Fe, Mg, and Zn.
1. Cu <Fe<Zn< Al< Mg
2. Zn< Fe< Cu< Mg< Al
3. Mg<Cu <Zn <Fe< Al
4. Al<Zn<Fe< Cu< Mg
Given the standard electrode potentials:
K+/K = –2.93 V |
Ag+/Ag = 0.80 V |
Hg2+/Hg = 0.79 V |
Mg2+/Mg = –2.37 V |
Cr3+/Cr = – 0.74 V |
1. | Cr < Mg < K < Ag < Hg | 2. | Mg < K < Ag < Hg < Cr |
3. | K < Ag < Hg < Cr < Mg | 4. | Ag < Hg < Cr < Mg < K |
The correct statement about the given galvanic cell equation is -
Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s)
1. | The current will flow from silver to zinc in the external circuit. |
2. | The current will flow from zinc to silver in the external circuit. |
3. | The current will flow from silver to zinc in the internal circuit. |
4. | The current will flow from zinc to silver in the internal circuit. |
2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
;
The value of in the above reaction will be-
1. | -196.83 kJ
|
2. | 196.83 kJ
|
3. | 186.83 kJ
|
4. | -186.83 kJ |
The incorrect statement(s) among the below is/are:
(a) | The unit of conductivity is S cm–2 |
(b) | Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration. |
(c) | The unit of molar conductivity is S cm2 mol–1 |
(d) | Molar conductivity increases with an increase in concentration. |
1. Only (a)
2. (a) and (d)
3. (b) and (d)
4. (a) and (c)
The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. The molar conductivity will be -
1. | 124 S cm2 mol-1 | 2. | 134 S cm2 mol-1 |
3. | 128 S cm2 mol-1 | 4. | 136 S cm2 mol-1 |
The electricity required in coulombs for the oxidation of 1 mole of FeO to is:
1. | 964.87 C | 2. | 96487 C |
3. | 96.487 C | 4. | 9.6487 C |
The value of Ecell in the reaction below will be:
\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)
\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)
1. +1.298 V
2. –1.398 V
3. –1.298 V
4. –1.198 V
The value of ∆G° in the reaction below would be:
\(\small{\mathrm{Zn}(\mathrm{s})+\mathrm{Ag}_2 \mathrm{O}(\mathrm{s})+\mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{Zn}^{+2}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})+2 \mathrm{OH}^{-}(\mathrm{aq})}\)
Given: \(E_{cell}^{\circ} = 1.04V\)
1. –2.13 kJ
2. –21.3 kJ
3. –201 kJ
4. –31.12 kJ
The mass of nickel deposited by electrolysis of a solution of using a current of 5 amperes for 20 min is:
(Atomic mass of Nickle is 58.7u)
1. 2.42 g
2. 1.82 g
3. 3.93 g
4. 6.42 g