The ionization constants of HCOOH, and HCN at 298K are 1.8 × 10–4 and 4.8 × 10–9 respectively. The ionization constants of the corresponding conjugate bases of HCOOH and HCN will be
1. | 5.6 × 10–11, 2.08 × 10–6
|
2. | 2.4 × 10–11, 4.2 × 10–6
|
3. | 3.5 × 10–11, 1.7 × 10–6
|
4. | 4.2 × 10–11, 1.2 × 10–6 |
The ionization constant of phenol is 1.0 × 10–10. The concentration of phenolate ion in 0.05 M solution of phenol will be:
1. | 4.2 × 10–4 M
|
2. | 3.6 × 10–5 M
|
3. | 7.8 × 10–6 M
|
4. | 2.2 × 10–6 M |
The first ionization constant of H2S is 9.1 × 10–8. The concentration of HS– ion in its 0.1 M solution will be:
1. | 12.3 × 10–7 M | 2. | 11.4 × 10–6 M |
3. | 3.5 × 10–4 M | 4. | 9.54 × 10–5 M |
The ionization constant of acetic acid is \(1.74 × 10^{–5}.\) The pH of acetic acid in its 0.05 M solution will be:
1. 7.81
2. 3.03
3. 8.54
4. 1.45
(a) Human muscle-fluid, pH = 6.83
(b) Human stomach fluid, pH = 1.2
(c) Human blood, pH = 7.38
(d) Human saliva, pH = 6.4.
Out of the above mentioned biological fluids, the one with the minimum concentration of hydrogen ions is:1. | Human blood | 2. | Human muscle fluid |
3. | Human stomach fluid | 4. | Human saliva |
The pH values of milk, tomato juice, lemon juice, and egg are 6.8, 4.2, 2.2, and 7.8 respectively.
The corresponding hydrogen ion concentration is maximum in:
1. | Lemon juice
|
2. | Milk
|
3. | Egg white
|
4. | Tomato juice |
The ionization constant of propanoic acid is 1.32 × 10–5. The degree of ionization of 0.05M acid solution will be:
1. = 0.63 × 10–2
2. = 1.63 × 10–4
3. = 1.63 × 10–2
4. = 0.05 × 10–2
The salt that gives a neutral solution in water is:
1. | KBr
|
2. | NH4NO3
|
3. | NaCN | 4. | Rb2(CO3) |
The ionization constant of benzoic acid is 6.46×105 and Ksp for silver benzoate is 2.5×10–13. Silver benzoate is x times more soluble in a buffer of pH 3.19 compared to its solubility in pure water. The value of x will be:
1. 6.8
2. 16.8
3. 33.3
4. 3.3
Consider the following reaction:
\(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2(\mathrm{~s}) \rightleftharpoons 2 \mathrm{CuO}(\mathrm{~s})+4 \mathrm{NO}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g})\)
What is the equilibrium constant \(K_c\) expression for the above reaction?