Consider the following reactions :

2 S2O32–(aq) + I2(s)  S4O62–(aq) + 2I(aq)

S2O32–(aq) + 2Br2(l) + 5H2O(l)  2SO42–(aq) + 4Br(aq) + 10H+(aq)

The same reductant, thiosulphate reacts differently with iodine and bromine because:

1. Br2 is a stronger oxidizing agent than I2

2. I2 is a stronger oxidizing agent than Br2

3. Both '1' and '2'

4. Neither '1' nor '2'

Subtopic:  Oxidizing & Reducing Agents |
 69%
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The correct statement(s) about the given reaction is -

\(\mathrm{{X} eO_{6 (aq)}^{4 -} + 2 F^{- 1}_{(aq)} + 6 H^{+}_{(aq )} \rightarrow}~\mathrm{{X} eO_{3 (g)} + {F}_{2 (g)} + 3 H_{2} O_{(l)}}\)

1. XeO64- oxidises F-

2. The oxidation number of F increases from -1  to  zero

3. XeO64- is a stronger oxidizing agent that F-

4. All of the above.

Subtopic:  Introduction to Redox and Oxidation Number | Oxidizing & Reducing Agents |
 87%
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Consider the following reactions:

Consider the following reactions:

(a) H3PO2(aq) + 4AgNO3(aq) + 2H2O(l) H3PO4(aq) + 4Ag(s) + 4HNO3(aq)

(b) H3PO2(aq) + 2CuSO4(aq) + 2H2O(l) H3PO4(aq) + 2Cu(s) + H2SO4(aq)

c C6H5CHO(l) + 2AgNH32+(aq) + 3OH-(aq)C6H5COO-(aq) + Ag(s) + 4NH3(aq) +H2O(l)(d) C6H5CHO(l) + 2Cu2+(aq) + 5OH-(aq)No change observed

Draw the inference about the behaviour of Ag+ and Cu2+ ions from these reactions 

1. Ag+ is a stronger oxidizing agent than Cu2+

2. Cu2+ is a stronger oxidizing agent than Ag+

3. Ag+ and Cu2+ are reducing agents

4.  Ag+ is a reducing agent and Cu2+ is an oxidising agent

Subtopic:  Oxidizing & Reducing Agents |
 66%
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The oxidising agent and reducing agent in the given reaction are

5P4s+12H2Ol+12HO-aq
8PH3g+12HPO2-aq

1. Oxidising agent = P4; Reducing agent = P4

2. Oxidising agent = P4; Reducing agent = H2O

3. Oxidising agent = H2O; Reducing agent = P4

4. None of the above

Subtopic:  Redox Titration & Type of Redox |
 70%
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The correct statement about the given reaction is-

(CN)2(g) + 2OH-(aq) CN-(aq) + CNO-(aq) + H2O(l)

1. The reaction is an example of a disproportionation reaction.
2. Hydrogen atom gets oxidized.
3. Reaction occurs in acidic medium.
4. None of the above

Subtopic:  Emf & Electrode Potential |
 82%
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The Mn3+ ion is unstable in solution and undergoes disproportionation reaction to give Mn2+, MnO2 and H+ ion. The balanced ionic equation for the reaction is-

1. \(\small{2 \mathrm{Mn}^{3+}{ }_{(\mathrm{aq})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow \mathrm{MnO}_{2(\mathrm{~s})}+\mathrm{Mn}^{2+}{ }_{(\mathrm{aq})}+4 \mathrm{H}^{+}{ }_{(\mathrm{aq})}}\)
2. Mn3+(aq) + H2O(l) → MnO2(s) + 2Mn2+(aq) + 4H+(aq)
3. \(\small{5 \mathrm{Mn}^{3+}(\mathrm{aq})+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow \mathrm{MnO}_{2(\mathrm{s})}+3 \mathrm{Mn}^{2+}(\mathrm{aq})+4 \mathrm{H}^{+}(\mathrm{aq})}\)
4. \(\small{2 \mathrm{Mn}^{3+}{ }_{(\mathrm{aq})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow 2 \mathrm{MnO}_{2(\mathrm{s})}+2 \mathrm{Mn}^{2+}{ }_{(\mathrm{aq})}+4 \mathrm{H}^{+}{ }_{(\mathrm{aq})}}\)

Subtopic:  Emf & Electrode Potential |
 80%
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Which element exhibits both positive and negative oxidation states?
1. Cs
2. Ne
3. I
4. F

Subtopic:  Introduction to Redox and Oxidation Number |
 64%
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The balanced equation for the reaction between chlorine and sulphur dioxide in water is:

1. Cl2(s) + SO2(aq) + 2H2O(I) →2Cl-(aq) + SO42-(aq) + 4H+(aq)
2. 3Cl2(s) + SO2(aq) + 2H2O(I) →Cl-(aq) + SO42-(aq) + 3H+(aq)
3. Cl2(s) + 3SO2(aq) + H2O(I) →Cl-(aq) + 2SO42-(aq) + 4H+(aq)
4. 2Cl2(s) + SO2(aq) + H2O(I) →2Cl-(aq) + SO42-(aq) + 4H+(aq)

Subtopic:  Balancing of Equations |
 84%
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The set of metals that can show disproportionation reaction is:
1. Cu, Na, Li
2. Mg, F, Ne
3. P, Cl, S
4. Mn, Cu, Ga

Subtopic:  Redox Titration & Type of Redox |
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The maximum weight of nitric oxide that can be obtained starting only with 10.00 g of ammonia and 20.00 g of oxygen is:

1. 9 g 2. 15 g
3. 12 g 4. 11g
Subtopic:  Balancing of Equations |
 64%
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