The van't Hoff factor of a 0.005 M aqueous solution of KCl is 1.95. The degree of ionisation of KCl is-
1. 0.95
2. 0.97
3. 0.94
4. 0.96
K4[Fe(CN)6] is 60% ionised. Then the value of Van't Hoff factor is
1. 1.6
2. 2.4
3. 3
4. 3.4
The temperature dependent term among the following is -
1. | Molality | 2. | Molarity |
3. | Mole fraction | 4. | Weight percentage |
Which one is not equal to zero for an ideal solution?
1. ΔHmix
2. ΔSmix
3. ΔVmix
4. ΔP=PObserved-PRaoult
Which one of the following elctrolytes has the same value of van't Hoff's factor(i) as
that of Al2(SO4)3 (if all are 100% ionised)?
1. K2SO4
2. K3[Fe(CN)6]
3. Al(NO3)3
4. K4[Fe(CN)6]
Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing
point depression?
1. KCl
2. C6H12O6
3. Al2(SO4)3
4. K2SO4
6.02 x 1020 molecules of urea are present in 100 mL of its solution. The concentration of the solution is:
1. | 0.02 M | 2. | 0.01 M |
3. | 0.001 M | 4. | 0.1 M |
The van't Hoff factor, i for a compound which undergoes dissociation in one solvent and
association in other solvent is respectively.
1. less than one and less than one
2. greater than one and less than one
3. greater than one and greater than one
4. less than one and greater than one
One litre aqueous solution of sucrose (molar mass = 342 g/mol) weighing 1015 g is found to record an osmotic pressure of 4.8 atm at 293K. What is the molality of the sucrose solution ? (R= 0.0821 L atm K-1 mol-1) :
(1) 0.84
(2) 0.21
(3) 0.42
(4) 0.63
1. There is a positive deviation from Raoult's law.
2. There is a negative deviation from Raoult's law.
3. There is no deviation from Raoult's law.
4. None of the above.