Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
The correct order for boiling points of the following compounds is:
1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
Chlorine shows the bleaching action in the presence of moisture due to the formation of
1. HOCl
2. HOClO
3. H2O2
4. O
1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
(a) | F–F bond has a low enthalpy of dissociation. |
(b) | Flouride ion (F–) has high hydration enthalpy. |
(c) | Electron gain enthalpy of fluorine is less negative than chlorine. |
(d) | Fluorine has a very small size. |
1. | (a) and (b) only | 2. | (a) and (c) only |
3. | (a) and (d) only | 4. | (b) and (c) only |
Assertion (A): | ICl is more reactive than I₂. |
Reason (R): | I-Cl bond is weaker than I-I bond. |
1. | (A) is False but (R) is True. |
2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
4. | (A) is True but (R) is False. |
List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
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A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
B. | Sulphuric acid | II. | Two S-OH, One S=O |
C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
Options: | A | B | C | D |
1. | III | IV | II | I |
2. | I | III | II | IV |
3. | III | IV | I | II |
4. | I | III | IV | II |
1. | It is a radioactive substance. |
2. | It is a very stable substance. |
3. | Half-life of Radon is longer. |
4. | It forms variety of compounds. |
Sea is the greatest source of :
1. Halogens.
2. Noble gases.
3. Alkaline earth metals.
4. Chalcogens.