The stability of 2,3-dimethyl but-2-ene is more than 2-butene. This can be explained in terms of:
1. resonance
2. hyperconjugation
3. electromeric effect
4. inductive effect
Who pointed out the concept of hyperconjugation?
(1) Nathan and Baker
(2) Mulliken
(3) Kekule
(4) Kolbe
(CH3)4N+ is neither an electrophile, nor a nucleophile because it:
1. does not have electron pair for donation as well as cannot attract electron pair
2. neither has electron pair available for donation nor can accommodate electron since all shells of N are fully occupied.
3. can act as Lewis acid and base
4. none of the above
Which of the following is the most unlikely resonance structure for the p-nitrophenoxide ion?
1. | 2. | ||
3. | 4. |
Which of the following is an electrophilic reagent?
1. RO-
2. BF3
3. NH3
4. ROH
The +I (inductive effect) is shown by:
1. -CH3
2. -OH
3. -F
4. -C6H5
The-I effect is shown by:
1. -COOH
2. -CH3
3. -CH3CH2
4. -CHR2
Which of the following is singlet carbene?
1. (CH3)3C+
2. C2H5-CH
3.
4. CH2 =CH-
Arrange H, CH₃, C₂H₅, and C₃H₇ in order of increasing positive inductive effect:
1. H < CH3 < C2H5 < C3H7
2. H> CH3 <C2H5 > C3H7
3. H < C2H5 < CH3 <C3H7
4. None of the above
To which ring size cycloalkanes, Baeyer’s strain theory is not valid?
(1) 3 carbon
(2) 4 carbon
(3) 5 carbon
(4) ≥6 carbon