If there is no rotation of plane polarized light by a compound in a specific solvent, thought to be chiral,
it may mean that:
(1) the compound is certainly a chiral
(2) the compound is certainly meso
(3) there is no compound in the solvent
(4) the compound may be a racemic mixture
For the following :
(i) I-
(ii) Cl-
(iii) Br-
the increasing order of nucleophilicity would be :
1. I- < Br- < Cl-
2. Cl- < Br- < I-
3. I- < Cl- < Br-
4. Br- < Cl- < l-
The stability of carbanions in the following
(1)
(2)
(3)
(4)
is in the order of
(a) (1)>(2)>(3)>(4)
(b) (2)>(3)>(4)>(1)
(c) (4)>(2)>(3)>(1)
(d) (1)>(3)>(2)>(4)
A strong base can abstract an -hydrogen from
1. alkene
2.amine
3. ketone
4. alkane
Which one of the following is most reactive towards electrophillic attack?
(a)
(b)
(c)
(d)
The relative reactivates of acyl compounds towards nucleophilic substitution are in the order of
(1) Acyl chloride > Acid anhydride > Ester > Amide
(2) Ester > Acyl Chloride > Amide > Acid anhydride
(3) Acid anhydride > amide > Ester > Acyl chloride
(4) Acyl chloride > Ester > Acid anhydride > Amide
The IUPAC name of the compound having the formula CHC-CH=CH2 is
1. 3-butene-1-yne
2. 1-butyn-3-ene
3. but-1-yne-3-ene
4. 1-butene-3-yne
Which one is most reactive towards electrophilic reagent?
Among the given compounds, the most susceptible to nucleophilic attack at the carbonyl group is
1. CH3COOCH3
2. CH3CONH2
3. CH3COOCOCH3
4. CH3COCl
The correct order of increasing reactivity of C-X bond towards nucleophile in the following
compounds is
1. I < II < IV < III
2. II < III < I < IV
3. IV < III < I < IV
4. III < II < I < IV