Based on the given data, what is the value of the molar conductivity at infinite dilution (Λm) for SrCl₂ in water at 25°C?

( Conc. (mol/lt)    0.25  1
(  Λ m–1 cm2 mol–1)1 260     250

1. 270

2. 260

3. 250

4. 255

Subtopic:  Conductance & Conductivity |
 56%
Level 3: 35%-60%
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During electrolysis of conc. H2SO4, perdisulphuric acid (H2S2O8), and O2
form in equimolar amount. The amount of H2 that will form simultaneously will be : 

1. Thrice that of O2 in moles.

2. Twice that of O2 in moles.

3. Equal to that of O2 in moles.

4. Half of that of O2 in moles.

Subtopic:  Faraday’s Law of Electrolysis |
Level 3: 35%-60%
Hints

For the hypothetical electrochemical cell given below:

A | A⁺(x M) || B⁺(y M) | B .

The measured cell emf is +0.20 V. Find the overall cell reaction.

1. A+ B → A + B+

2.  A+ e→  A ; B+ e→ B

3.  The cell reaction cannot be predicted

4.  A + B→ A+ B

Subtopic:  Nernst Equation |
 73%
Level 2: 60%+
NEET - 2006
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The efficiency of a fuel cell is given by:

(a)H/G(b)G/S
(c)G/H(d)S/G

Subtopic:  Hydrogen Economy |
 67%
Level 2: 60%+
NEET - 2007
Hints

Limiting molar conductivity of NH4OH (i.e Åm(NH4OH)) is equal to:-

1. Åm (NH4Cl)+Åm(NaCl)-Åm(NaOH) 

2. Åm(NaOH)+Åm(NaCl)-Åm(NH4Cl)

3. Åm(NH4OH)+Åm(NH4Cl)-Åm(HCl)

4. Å(NH4Cl)+Å(NaOH)-Å(NaCl)

Subtopic:   Kohlrausch Law & Cell Constant |
 83%
Level 1: 80%+
NEET - 2012
Hints

A button cell used in watches functions as following

Zn(s) + Ag2O(s) + H2O (l) 2Ag(s) + Zn2+(aq) + 2OH-(aq)

If half cell potentials are

Zn2+aq+2e-Znx;Eo=-0.76VAg2Os+H2Ol+2e-2Ags+2OH-aq;Eo=0.34V

The cell potential will be

1. 0.84 V

2. 1.34 V

3. 1.10 V

4. 0.42 V

 

 

Subtopic:  Electrolytic & Electrochemical Cell |
 82%
Level 1: 80%+
NEET - 2013
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What is the value of pKb(CH3COO-) if λm0=390&λm=7.8 for 0.04 of a CH3COOH  at 25°C ?

(A) 9.3                                               

(B) 9.2

(C) 4.7                                               

(D) 4.8

Subtopic:  Conductance & Conductivity |
 63%
Level 2: 60%+
Hints

Calculate the equilibrium constant (K) for a reaction involving a two-electron transfer,
 if the standard emf of the cell at 25°C is 0.295 V.

1.2.95 × 10⁻²

2.1.0 × 10¹

3.    2.95 × 10¹⁰

4.   1.0 × 10¹⁰

Subtopic:  Relation between Emf, G, Kc & pH |
Level 4: Below 35%
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How much current is necessary to produce H2 gas at the rate of 1 cm3 per second under STP ?

(A) 4.305 amp                                           

(B) 17.22 amp

(C) 8.61 amp                                            

(D) 2.1525 amp.

Subtopic:  Faraday’s Law of Electrolysis |
 60%
Level 2: 60%+
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During discharge of a lead storage cell, the density of sulphuric acid in the cell-

1. Increases.                                     

2. Decreases.

3. Remains unchanged.                      

4. Initially increases but decreases subsequently.

Subtopic:  Electrolytic & Electrochemical Cell |
 66%
Level 2: 60%+
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