Acidified permanganate solution does not oxidize:

(1) C2O42-(aq)                   

(2) NO2-(aq)

(3) S2-(aq)                         

(4) F-(aq)

Subtopic:  Chemistry of Mn and Cr Compounds |
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Which of the following statements is incorrect?

1. Transition elements exhibit higher enthalpies of atomization as they have stronger interatomic interaction.
2. IE2 of V23<Cr24>Mn25 and Ni28<Cu29>Zn30.
3. Ni(II) compounds are more stable than Pt(II) whereas Pt(IV) compounds are more stable than nickel(IV)
4. The elements which give the greatest number of oxidation states do not occur in or near the middle of the series.

Subtopic:  d-Block Elements- Properties & Uses |
 76%
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Which of the following is true for the species 3d4 configuration ?

(1) Cr2+ is reducing in nature                               

(2) Mn3+ is oxidising in nature.

(3) Both (A) and (B)                                             

(4) None of these

Subtopic:  d-Block Elements- Properties & Uses |
 78%
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In which compound does vanadium have an oxidation number of +4?

(A) NH4VO2                                 

(B) K4VCN6

(C) VSO4                                     

(D) VOSO4

Subtopic:  d-Block Elements- Properties & Uses |
 66%
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Among the following, the species that is both paramagnetic and coloured is :

(A) MnO42-                                     

(B) TiCl62- 

(C) VO43-                                       

(D) CrO2Cl2

Subtopic:  d-Block Elements- Properties & Uses |
 73%
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Arrange the following species in the increasing order of their magnetic properties.

VCl3    VOSO4    Na3VO4       VH2O6SO4.H2O

  I              II                  III                      IV

 

(1) III<II<I<IV                                         

(2) III<IV<II<I

(3) II<III<I<IV                                         

(4) IV<I<II<III

Subtopic:  d-Block Elements- Properties & Uses |
 56%
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Which of the following increasing order of oxidising power is correct for the following species?

           VO2+, MnO4-, Cr2O72-

(A) VO2+<Cr2O72-<MnO4-                           

(B) VO2+<MnO4-<Cr2O72-

(C) Cr2O72-<VO2+<MnO4-,                           

(D) Cr2O72-<MnO4-<VO2+

Subtopic:  d-Block Elements- Properties & Uses |
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In which of the following oxoanions the oxidation state of the central atom is not the same as that of its group number in the periodic table?

(A) MnO4-                               

(B) Cr2O72-

(C) VO43-                                 

(D) FeO42-

Subtopic:  d-Block Elements- Properties & Uses |
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At 300°C, FeCl3 :

1. Decomposes into FeCl2 and Cl2.               

2. Decomposes into Fe and Cl2.

3. Sublimes go give liquid FeCl3                         

4. Sublimes to give gaseous dimmer FeCl32.

Subtopic:  Chemistry of Mn and Cr Compounds |
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Anhydrous ferric chloride is prepared by

(1) Heating hydrated ferric chloride at a high temperature in a stream of air.

(2) Heating metallic iron in a stream of dry chlorine gas.

(3) Reaction of ferric oxide with HCl (aq).

(4) Reaction of metallic iron with HCl (aq).

Subtopic:  Chemistry of Mn and Cr Compounds |
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