What is the resulting change in the internal energy of the system when 50 calories are added to
the system and the system does work of 30 calories on the surroundings?

1. 20 cal                             
2. 50 cal
3. 40 cal                             
4. 30 cal

Subtopic:  Enthalpy & Internal energy |
 92%
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For the process:

H2O(l)[1 bar, 373 K] H2O(g)[1 bar, 373 K] the correct set of thermodynamic parameters are:

1. G=0; S=+ve

2. G=0; S=-ve

3. G=+ve; S=0

4. G=-ve; S=+ve

Subtopic:  Spontaneity & Entropy |
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The internal energy change when a system goes from state A to B is 40 kJ/mol. If the system goes from A to B by a reversible path and returns to state A by an irreversible path. What would be the change in internal energy?

1. 40 kJ                                   

2. >40 kJ

3. <40 kJ                                 

4. Zero

Subtopic:  2nd & 3rd Law of Thermodynamics |
 61%
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Change in entropy is negative for:

1. Bromine (l)Bromine(g)

2. C(s) + H2O(g) CO(g) + H2(g)

3. N2(g,10 atm)N2(g,1 atm) 

4. Fe ( 1mol, 400 K)  Fe( 1mol, 300 K)

Subtopic:  Spontaneity & Entropy |
 66%
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The mathematical form of the first law of thermodynamics when heat (q) is supplied and W is work done by the system (-ve) is:

1. U=q+W                       

2. U=q-W

3. U=-q+W                       

4. U= -q-W

Subtopic:  2nd & 3rd Law of Thermodynamics |
 59%
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Which statements are correct?

1. 2.303 logP2P1=Hvap.RT2-T1T1T2 is called Clausius-Clapeyron equation

2. Hvap.Boiling Point=88 J mol-1K-1 is called Trouton's rule

3. Entropy is a measure of unavailable energy, i.e.,

     unavailable energy = entropy x temperature

4. All of the above

 

Subtopic:  Enthalpy & Internal energy |
 80%
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S° will be highest for the reaction:

1. Ca(s) + 1/2 O2(g) CaO(s)

2. CaCO3(s)CaO(s) + CO2(g)

3. C(s) + O2(g)CO2(g)

4. N2(g) + O2(g)2NO(g)

Subtopic:  Spontaneity & Entropy |
 71%
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One mole of ice is converted to water at 273 K. The entropies of H₂O(s) and H₂O(l) are 38.20 J mol⁻¹K⁻¹ and 60.01 J mol⁻¹K⁻¹, respectively. What is the enthalpy change for this conversion?

1. 59.54 J mol-1                               

2. 5954 J mol-1

3. 595.4 J mol-1                             

4. 320.6 J mol-1

Subtopic:  Spontaneity & Entropy |
 73%
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A gaseous system changes from state A(P1, V1, T1) to B(P2,V2,T2), B to C(P3, V3, T3) and finally from C to A. The whole process may be called:

1. reversible process                           

2. cyclic process

3. isobaric process                               

4. spontaneous process

Subtopic:  Thermodynamics' Properties and process |
 87%
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When one mole of monoatomic ideal gas at TK undergoes reversible adiabatic change under a constant external pressure of 1 atm changes volume from 1 litre to 2 litre. The final temperature in kelvin would be:

1. T/(2)2/3                                         

2. T + 2/(3x0.0821)

3. T                                                   

4. T - 3/(2x0.0821)

Subtopic:  Cp & Cv |
 51%
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