Two isomeric ketones 3-Pentanones and 2-Pentanone can be distinguished by:

1. I₂/NaOH only               

2. NaHSO₃ only

3. NaCN/HCl                     

4. Both of (a) and (b)   

Products of the following reaction                                   

  CH₃C$\equiv$C-CH₂CH₃ $\underset{\left(\mathrm{ii}\right) \mathrm{hydrolysis}}{\overset{\left(\mathrm{i}\right) {\mathrm{O}}_3}{\to }}$ ... are

1. CH₃CHO + CH₃CH₂CHO

2. CH₃COOH + CH₃COCH₃

3. CH₃COOH + HOOC-CH₂CH₃

4. CH₃COOH + CO₂

Which alkene on ozonolysis gives CH₃CH₂CHO and CH₃COCH₃?                                          

1. CH₃CH₂CH=C${<}_{{\mathrm{CH}}_3}^{{\mathrm{CH}}_3}$

2. CH₃CH₂CH=CHCH₂CH₃

3. CH₃CH₂CH=CHCH₃

4. ${\mathrm{CH}}_3-\underset{|}{\mathrm{C}}={\mathrm{CHCH}}_3$
${\mathrm{CH}}_3$

Benzoic acid gives benzene on being heated with X and phenol gives benzene on being heated with Y. Therefore, X and Y are respectively                                                              

1. Sodalime and copper

2. Zn dust and NaOH

3. Cu and sodalime

4. Sodalime and zinc dust

Which one of the following on oxidation gives a ketone?                       

1. primary alcohol                     

2. secondary alcohol

3. tertiary alcohol                     

4. All of these

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of $\mathrm{\alpha }$-hydroxy acid. The carbonyl compound is

1. acetaldehyde 

2. acetone

3. diethyl ketone 

4. formaldehyde                              

Consider the following transformations

CH₃COOH $\stackrel{{\mathrm{CaCO}}_3}{\to }$A$\stackrel{\mathrm{heat}}{\to }$B$\underset{\mathrm{NaOH}}{\overset{{\mathrm{I}}_2}{\to }}$C The molecular formula of C is                       

1. ${\mathrm{CH}}_3-\underset{\mathrm{I}}{\overset{\mathrm{OH}}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_3$

2. ${\mathrm{ICH}}_2-{\mathrm{COCH}}_3$

3. ${\mathrm{CHI}}_3$

4. ${\mathrm{CH}}_3\mathrm{I}$

The product formed in aldol condensation is                                                                 

1. a beta-hydroxy acid

2. a beta-hydroxy aldehyde or a beta-hydroxy ketone

3. an alpha-hydroxy aldehyde or ketone

4. an alpha, beta unsaturated ester

Consider the following reaction,

Phenol$\stackrel{\mathrm{Zn}-\mathrm{dust}}{\to }$X$\underset{\mathrm{Anhy}.{\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}$Y$\stackrel{\mathrm{Alk}.{\mathrm{KMnO}}_4}{\to }$Z 

The product Z is                            

1. toluene

2. benzaldehyde

3. benzoic acid

4. benzene

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called    

1. Clemmenson reduction

2. Cope reduction

3. Dow reduction

4. Wolff-Kishner reduction