CH₃-C$\equiv$C-H$\stackrel{{\mathrm{CH}}_3\mathrm{MgBr}}{\to }$CH₄ + (A)$\underset{\left(\mathrm{ii}\right) {\mathrm{H}}_2\mathrm{O}/{\mathrm{H}}^{+}}{\overset{\left(\mathrm{i}\right) {\mathrm{CO}}_2}{\to }}$(B); (B) is -

1. H₃C-CH₂-CH₂-COOH

2. CH₃-C$\equiv$C-CH₃

3. H₃C-C$\equiv$C-COOH

4. H₃C-CH=CH-COOH

3-Hexyne can be converted to trans-3-Hexene by the action of:

1. ${\mathrm{H}}_2$ - Pd/ ${\mathrm{BaSO}}_4$                       

2. Li-Liq. ${\mathrm{NH}}_3$

3. ${\mathrm{H}}_2$ - Pt ${\mathrm{O}}_2$                               

4. ${\mathrm{NaBH}}_4$

A compound having the shortest carbon-carbon bond length among the following is :

1. Benzene                                 

2. Ethene

3. Ethyne                                   

4. Ethane

Reaction of HBr with propene in the presence of peroxide gives

1. iso-propyl bromide

2. 3-bromo propane

3. allyl bromide

4. n-propyl bromide

In the reaction, ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_3\stackrel{\mathrm{Oxidation}}{\to }$A $\stackrel{\mathrm{NaOH}}{\to }$B$\underset{∆}{\overset{\mathrm{Soda} \mathrm{lime}}{\to }}$C 

the product C is:

1. ${\mathrm{C}}_6{\mathrm{H}}_5\mathrm{OH}$ 

2. ${\mathrm{C}}_6{\mathrm{H}}_6$

3. ${\mathrm{C}}_6{\mathrm{H}}_5\mathrm{COONa}$

4. ${\mathrm{C}}_6{\mathrm{H}}_5\mathrm{ONa}$

The compound formed when acetylene is passed through dilute sulphuric acid in the presence of mercury(II) sulphate is:

1. Ether

2. Ketone

3. Acetic acid

4. Acetaldehyde

Acetylenic hydrogens are acidic because

1. sigma electron density of C-H bond in acetylene is nearer to carbon which has 50% s-character

2. acetylene has only one hydrogen on each carbon

3. acetylene contains least number of hydrogens among the possible hydrocarbons having two carbons

4. acetylene belong to the class of alkynes with molecular formula ${\mathrm{C}}_{\mathrm{n}}{\mathrm{H}}_{2\mathrm{n}-2}$

A compound is treated with ${\mathrm{NaNH}}_2$ to give sodium salt. Identify the compound.

1. ${\mathrm{C}}_2{\mathrm{H}}_2$ 

2. ${\mathrm{C}}_6{\mathrm{H}}_6$

3. ${\mathrm{C}}_2{\mathrm{H}}_6$ 

4. ${\mathrm{C}}_2{\mathrm{H}}_4$

Which alkene on ozonolysis gives ${}_{}$
 \(CH_3CH_2CHO\) and  \(CH_3CCH_3\\ ~~~~~~~~||\\ ~~~~~~~~O\) 

1.

2. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CH}={\mathrm{CHCH}}_2{\mathrm{CH}}_3$

3. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CH}={\mathrm{CHCH}}_3$

4. 

Hydroxylation of propyne in the presence of ${\mathrm{HgSO}}_4/{\mathrm{H}}_2{\mathrm{SO}}_4$ is initiated by the attack of:

1. carbene 

2. free radical

3. electrophile

4. nucleophile