A mixture of ethane, ethene and ethyne is passed through an ammoniacal ${\mathrm{AgNO}}_3$ solution. The gases that remain unreacted are-

1. Ethane and Ethene 

2. Ethane and Ethyne

3. Ethene and Ethyne 

4. Ethane only

Which is the most suitable reagent among the following to distinguish compound (III) from rest of the compounds?

I. ${\mathrm{CH}}_3-\mathrm{C}\equiv \mathrm{C}-{\mathrm{CH}}_3$

II. ${\mathrm{CH}}_3-{\mathrm{CH}}_2-{\mathrm{CH}}_2-{\mathrm{CH}}_3$

III. ${\mathrm{CH}}_3-{\mathrm{CH}}_2-\mathrm{C}\equiv \mathrm{CH}$

IV. ${\mathrm{CH}}_3-\mathrm{CH}={\mathrm{CH}}_2$

The reaction, 

${\mathrm{C}}_6{\mathrm{H}}_6$ + ${\mathrm{CH}}_3\mathrm{Cl}\underset{{\mathrm{AlCl}}_3}{\overset{\mathrm{Anhydrous}}{\to }}$${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_3$ + HCl

is an example of:

1. Friedel-Crafts reaction

2. Kolbe's synthesis

3. Wurtz's reaction

4. Grignard synthesis

Ozonolysis of will give:
 

1.		2.
3.		4.	None of the above

2-Methylpropene and But-1-ene can be distinguished by:

1. Baeyer's reagent

2. Ammoniacal ${\mathrm{AgNO}}_3$

3. ${\mathrm{Br}}_2$ solution 

4. ${\mathrm{O}}_3$, $\mathrm{Zn}/{\mathrm{H}}_2\mathrm{O}$

An octane number 100 is given to:

1. n-hexane

2. Iso-octane 

3. neo-pentane

4. neo-octane 

Which of the following molecules/species are aromatic in character?

     A                      B                          C                               D

1. B

2. C

3. D

4. A

Xylene, on oxidation with acidic ${\mathrm{KMnO}}_4$, gives:

Nitration of benzene is:

1. nucleophilic substitution

2. electrophilic substitution

3. electrophilic addition

4. nucleophilic addition

Which of the following compounds has the lowest boiling point?

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$

2. ${\mathrm{CH}}_3\mathrm{CH}=\mathrm{CH}-{\mathrm{CH}}_2{\mathrm{CH}}_3$

3. ${\mathrm{CH}}_3\mathrm{CH}=\mathrm{CH}-\mathrm{CH}={\mathrm{CH}}_2$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$