Benzene reacts with ${\mathrm{CH}}_3\mathrm{Cl}$ in the presence of anhy. ${\mathrm{AlCl}}_3$ to form

1. toluene

2. chlorobenzene

3. benzylchloride

4. xylene

 

$\mathrm{CH}\equiv \mathrm{CH}\stackrel{{\mathrm{O}}_3/\mathrm{NaOH}}{\to }$X$\stackrel{\mathrm{Zn}/{\mathrm{CH}}_3\mathrm{COOH}}{\to }$Y. Y is:

1. ${\mathrm{CH}}_2\mathrm{OH}-{\mathrm{CH}}_2\mathrm{OH}$ 

2. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}$

3. ${\mathrm{CH}}_3\mathrm{COOH}$ 

4. ${\mathrm{CH}}_3\mathrm{OH}$

Alkynes can be reduced to alkenes by hydrogenation in presence of:

1. raney Ni 

2. anhy. ${\mathrm{AlCl}}_3$

3. Pd 

4. Lindlar's catalyst

Octane no. of a fuel can be increased by:

1. isomerism 

2. alkylation

3. reforming 

4. all of these

The shortest $\mathrm{C}-\mathrm{C}$ bond distance is found in:

1. Diamond 

2. Ethane

3. Benzene

4. Acetylene

Benzene reacts with n-propyl chloride in the presence of anhydrous ${\mathrm{AlCl}}_3$ to give

1. 3-propyl-1-chlorobenzene

2. n-propyl benzene

3. no reaction

4. iso-propyl benzene

The distance between two adjacent cabron atoms is largest in

1. benzene 

2. ethene

3. butane

4. ethyne

In benzene, $\mathrm{C}-\mathrm{C}$ bond length is 1.39 $\stackrel{°}{\mathrm{A}}$; the $\mathrm{C}-\mathrm{H}$ bond length is:

1. 1.39 

2. 1.08

3. 1.54

4. 1.46

Which reaction produces acrylonitrile (${\mathrm{CH}}_2=\mathrm{CHCN}$)?

1. Ethyne $\underset{{\mathrm{Ba}}^{2+}}{\overset{\mathrm{HCN}}{\to }}$                           

2. Acrylic acid $\stackrel{\mathrm{KCN}}{\to }$

3. Ethyne $\stackrel{\mathrm{KCN}}{\to }$                           

4. Ethyne $\stackrel{\mathrm{HOCl}}{\to }$

 is not converted to  by:

1. Wolff-Kishner reaction

2. Clemmensen reduction

3. Red P + HI at $200°\mathrm{C}$

4. Wurtz's reaction