Which of the following aqueous solution has osmotic pressure nearest to that an equimolar solution of K₄[Fe(CN)₆]?

1. Na₂SO₄

2. BaCl₂

3. Al₂(SO₄)₃

4. C₁₂H₂₂O₁₁

The molar volume of liquid benzene (density= 0.877 g ml^-1) increases by a factor of 2750 as it vapourises at 20$°\mathrm{C}$. At 27$°\mathrm{C}$ when a non-volatile solute (that does not dissociate) is dissolved in 54.6cm3 of benzene, vapour pressure of this solution, is found to be 98.88 mm Hg. calculate the freezing point of the solution.

Given: Enthalpy of vapourisation of benzene(l)=394.57 Jg^-1. Enthalpy of fusion of benzene (l) = 10.06 kJ mol^-1 Molal depression constant for benzene=5.0 K kg mol^-1.

1. 177.65 K

2. 277.65 K

3. 517.65 K

4. 237.15 K

The depression in the freezing point of water when 10 g of CH₃CH₂CHClCOOH is added to 250 g of water is -K_a=1.4 X 10^-3, K_f=1.86K kg mol^-1

1. 0.15$°\mathrm{C}$

2. 2.15$°\mathrm{C}$

3. 1.15$°\mathrm{C}$

4. 0.65$°\mathrm{C}$

The ratio of the vapour pressure of a solution to the vapour pressure of the solvent is

1. Equal to the mole fraction of the solvent

2. Proportional to the mole fraction of the solute

3. Equal to the mole fraction of the solute

4. None of the above

Mole fraction of the component A in vapour phase is X₁ and mole fraction of component A in liquid mixture is X₂ then 

(${\mathrm{P}}_{\mathrm{A}}^0$ = vapour pressure of pure A; ${\mathrm{P}}_{\mathrm{B}}^0$= vapour pressure of pure B),

then total vapour pressure of the liquid mixture is-

1. $\frac{{\mathrm{P}}_{\mathrm{A}}^0{\mathrm{X}}_2}{{\mathrm{X}}_1}$

2. $\frac{{\mathrm{P}}_{\mathrm{A}}^0{\mathrm{X}}_1}{{\mathrm{X}}_2}$

3. $\frac{{\mathrm{P}}_{\mathrm{B}}^0{\mathrm{X}}_1}{{\mathrm{X}}_2}$

4. $\frac{{\mathrm{P}}_{\mathrm{B}}^0{\mathrm{X}}_2}{{\mathrm{X}}_1}$

Given that the pH of a 0.1 M monobasic acid is 2, what is the osmotic pressure at a given temperature T?

1. 0.1RT

2. 0.11RT

3. 1.1RT

4. 0.01RT

The vapour pressure of pure water at 298K is 23.76mm. The vapour pressure of a solution of sucrose(C₁₂H₂₂O₁₁) in 5.56 moles of water is 23.392mm Hg. The mass of sucrose in the solution is

1. 15 g

2. 45 g

3. 30 g

4. 37.5 g

Which of the following 0.1 M aqueous solutions will have the lowest freezing point?

A 100.0g ice cube at 0.0°C is placed in 650g of water at 25°C . what is the final temperature of the mixture?

1. 11$°\mathrm{C}$

2. 12.5$°\mathrm{C}$

3. 18$°\mathrm{C}$

4. 16$°\mathrm{C}$

The vapour pressure of toluene is 59.1 torr at 313.75 K and 298.7 torr at 353.15 K. Calculate, the molar heat of vaporisation.

1. 37888 J mol^-1

2. 27188 J mol^-1

3.  12834 J mol^-1

4. 571328 J mol^-1