The ratio of the vapour pressure of a solution to the vapour pressure of the solvent is

1. Equal to the mole fraction of the solvent

2. Proportional to the mole fraction of the solute

3. Equal to the mole fraction of the solute

4. None of the above

Mole fraction of the component A in vapour phase is X₁ and mole fraction of component A in liquid mixture is X₂ then 

(${\mathrm{P}}_{\mathrm{A}}^0$ = vapour pressure of pure A; ${\mathrm{P}}_{\mathrm{B}}^0$= vapour pressure of pure B),

then total vapour pressure of the liquid mixture is-

1. $\frac{{\mathrm{P}}_{\mathrm{A}}^0{\mathrm{X}}_2}{{\mathrm{X}}_1}$

2. $\frac{{\mathrm{P}}_{\mathrm{A}}^0{\mathrm{X}}_1}{{\mathrm{X}}_2}$

3. $\frac{{\mathrm{P}}_{\mathrm{B}}^0{\mathrm{X}}_1}{{\mathrm{X}}_2}$

4. $\frac{{\mathrm{P}}_{\mathrm{B}}^0{\mathrm{X}}_2}{{\mathrm{X}}_1}$

Given that the pH of a 0.1 M monobasic acid is 2, what is the osmotic pressure at a given temperature T?

1. 0.1RT

2. 0.11RT

3. 1.1RT

4. 0.01RT

The vapour pressure of pure water at 298K is 23.76mm. The vapour pressure of a solution of sucrose(C₁₂H₂₂O₁₁) in 5.56 moles of water is 23.392mm Hg. The mass of sucrose in the solution is

1. 15 g

2. 45 g

3. 30 g

4. 37.5 g

Which of the following 0.1 M aqueous solutions will have the lowest freezing point?

A 100.0g ice cube at 0.0°C is placed in 650g of water at 25°C . what is the final temperature of the mixture?

1. 11$°\mathrm{C}$

2. 12.5$°\mathrm{C}$

3. 18$°\mathrm{C}$

4. 16$°\mathrm{C}$

The vapour pressure of toluene is 59.1 torr at 313.75 K and 298.7 torr at 353.15 K. Calculate, the molar heat of vaporisation.

1. 37888 J mol^-1

2. 27188 J mol^-1

3.  12834 J mol^-1

4. 571328 J mol^-1

The vapour pressure of a pure liquid solvent A is 0.80 atm. When a non-volatile substance B is added to the solvent, its vapour pressure drops to 0.60 atm.
Mole fraction of the component B in the solution is:

The lowest boiling point, if concentration is fixed at 0.1 M in aqueous solution, is given by which of the following solutions?

a. K₂SO₄

b. NaCl

c. Urea

d. Glucose

1. a, b

2. b, c

3. c, d

4. d, a

The boiling point of acetic acid is 118.1$°\mathrm{C}$ and its latent heat of vaporisation is 121 cal/gm. A solution containing 0.4344 gm anthracene in 44.16 gm acetic acid boils at 118.24$°\mathrm{C}$. What is the molecular wt. of anthracene ?

1. 122

2. 178

3. 105

4. 154