The standard reduction electrode potentials of three metals X, Y, and Z are given as -1.2 V, +0.5 V, and -3.0 V, respectively. Based on these values, what is the correct order of their reducing power?

1. Y > X >Z 2. Z > X > Y
3. X > Y > Z 4. Y > Z > X

Subtopic:  Electrochemical Series |
 82%
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During an electrolysis experiment, if a 100 mA current is passed through a solution of AgNO3 for 30 minutes, how many coulombs of electricity will be consumed?

1. 108 C

2. 18000 C

3. 180 C

4. 3000 C

Subtopic:  Faraday’s Law of Electrolysis |
 82%
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Standard reduction potentials at 25°C of Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are -3.05, -2.90, -2.71 and -2.37 V respectively. Which one of the following is the strongest oxidising agent ?

1. Mg2+

2. Ba2+

3. Na+

4. Li+

Subtopic:  Electrode & Electrode Potential |
 78%
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A galvanic cell is composed of two hydrogen electrodes, one of which is a standard one. In which of the following solutions should the other electrode be immersed to get maximum e.m.f.?

1. 0.1 M HCl

2. 0.1 M CH3COOH

3. 0.1 M H3PO2

4. 0.1 M H2SO4

Subtopic:  Electrode & Electrode Potential |
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For the cell, Ti|Ti+(0.001M)||Cu2+(0.1M)|Cu,Ecell at 25°C is 0.83 V. Ecell can be increased:

1. By increasing [Cu2+]

2. By increasing [Ti+]

3. By decreasing [Cu2+]

4. None of these

Subtopic:  Nernst Equation |
 69%
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A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI of pH = 10 and by passing hydrogen gas around the platinum wire at 1 atm pressure. The oxidation potential of the electrode would be:

1. 0.059 V
2. 0.59 V
3. 00.118 V
4. 1.18 V

Subtopic:  Electrode & Electrode Potential |
 77%
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The atomic mass of Al is 27. When a current of 5 faraday is passed through a solution of Al3+ ions, the mass of Al deposited is:

1. 27 g

2. 36 g

3. 45 g

4. 9 g

Subtopic:  Faraday’s Law of Electrolysis |
 85%
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On the basis of the information available from the reaction.

43Al + O2           23Al2O3, G =-827kJ mol-1 

of O2, the minimum EMF required to carry out the electrolysis of Al2O3 is : (F=96500 C mol-1

1. 2.14 V

2. 4.28 V

3. 6.42 V

4. 8.56 V

Subtopic:  Faraday’s Law of Electrolysis |
 63%
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For the reductidon of silver ions with copper metal, the standard  cell potential was found to be + 0.46 V at 250C. The value of standard Gibbs energy(G0) will be ;
(F = 96500 Cmol-1)

1. -89.0 KJ

2. -89.0 J

3. -44.5 KJ

4. -98.0 KJ

Subtopic:  Relation between Emf, G, Kc & pH |
 71%
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A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively:

1. H2, O2

2. O2, H2

3. O2, Na

4. O2, SO2

Subtopic:  Electrolytic & Electrochemical Cell |
 75%
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