The cell reaction for the given cell is spontaneous if:
Ptcl2|cl-(1M)||Cl-(1M)|PtCl2
1. P1 > P2
2. P1 < P2
3. P1 = P2
4. P1 = 1 atm
Each of the three metals X, Y and Z were put in turn into aqueous solution of the other two.
Which observation is probably incorrect?
1. Y + Salt of X = No action observed
2. Y + Salt of Z = Z + Salt of Y
3. Z + Salt of X = X + Salt of Z
4. Z + Salt of Y = No action observed
The standard reduction potentials of Cu2+/Cu and Cu2+/Cu+ are 0.337 and 0.153V respectively. The standard electrode potential of Cu+/Cu half cell is:
1. 0.184V
2. 0.827V
3. 0.521V
4. 0.490V
When a lead storage battery is discharged, then:
1. SO2 is evolved.
2. Lead is formed.
3. Lead sulphate is consumed.
4. Sulphuric acid is consumed.
The ratio of masses of hydrogen and magnesium deposited by the same amount of electricity from H2SO4 and MgSO4 in aqueous solution are:
1. 1:8
2. 1:12
3. 1:16
4. none of these
The molar conductances of Ba2+ and Cl- 127 and 76Ω-1 cm-1 mol-1 respectively at infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be
1. 139.52
2. 203
3. 279
4. 101.5
A depolariser used in dry cell batteries is:
1. Ammonium chloride
2. Manganese dioxide
3. Potassium hydroxide
4. Sodium phosphate
The reaction taking place at anode when an aqueous solution of CuSO4 is electrolysed using inert Pt electrode:
1. 2 S2 + 2e
2. Cu2+ + 2e Cu
3. 2H2O O2 + 4H+ + 4e
4. 2H+ +2e H2
An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to
1. increase in ionic mobility of ions
2. 100% ionisation of electrolyte at normal dilution
3. increase in both, i.e. number of ions and ionic mobility of ions
4. increase in number of ions
For the cell, Ti|Ti+(0.001M)||Cu2+(0.1M)|Cu,Ecell at 25C is 0.83 V. Ecell can be increased:
1. By increasing [Cu2+]
2. By increasing [Ti+]
3. By decreasing [Cu2+]
4. None of these