The cell reaction for the given cell is spontaneous if:

Ptcl2|cl-(1M)||Cl-(1M)|PtCl2

1. P1 > P2 

2. P1 < P2

3. P1 = P2

4. P1 = 1 atm

Subtopic:  Electrode & Electrode Potential |
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Each of the three metals X, Y and Z were put in turn into aqueous solution of the other two.

X + Salt of Y (or Z)   Y (or Z) + Salt of X.

Which observation is probably incorrect?

1. Y + Salt of X = No action observed

2. Y + Salt of Z = Z + Salt of Y

3. Z + Salt of X = X + Salt of Z

4. Z + Salt of Y = No action observed

Subtopic:  Electrochemical Series |
 59%
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The standard reduction potentials of Cu2+/Cu and Cu2+/Cu+ are 0.337 and 0.153V respectively. The standard electrode potential of Cu+/Cu half cell is:

1. 0.184V 

2. 0.827V

3. 0.521V

4. 0.490V

Subtopic:  Electrode & Electrode Potential |
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When a lead storage battery is discharged, then:

1. SO2 is evolved.

2. Lead is formed.

3. Lead sulphate is consumed.

4. Sulphuric acid is consumed.

Subtopic:  Batteries & Salt Bridge |
 59%
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The molar conductances of Ba2+ and Cl- 127 and 76Ω-1 cm-1 mol-1 respectively at infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be

1. 139.52

2. 203

3. 279

4. 101.5

Subtopic:   Kohlrausch Law & Cell Constant |
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A depolariser used in dry cell batteries is: 

1. Ammonium chloride 

2. Manganese dioxide

3. Potassium hydroxide 

4. Sodium phosphate

Subtopic:  Batteries & Salt Bridge |
 52%
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The reaction taking place  at anode when an aqueous solution of CuSO4 is electrolysed using inert Pt electrode:

1. 2SO42-  S2O32- + 2e

2. Cu2+ + 2e Cu

3. 2H2 O2 + 4H+ + 4e

4. 2H+ +2e  H2

Subtopic:  Electrode & Electrode Potential |
 67%
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An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to

1. increase in ionic mobility of ions

2. 100% ionisation of electrolyte at normal dilution

3. increase in both, i.e. number of ions and ionic mobility of ions

4. increase in number of ions

Subtopic:   Kohlrausch Law & Cell Constant |
 55%
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A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI of pH = 10 and by passing hydrogen gas around the platinum wire at 1 atm pressure. The oxidation potential of the electrode would be:

1. 0.059 V
2. 0.59 V
3. 00.118 V
4. 1.18 V

Subtopic:  Electrode & Electrode Potential |
 77%
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4.5 g of aluminium (atomic mass 27u) is deposited at cathode from Al3+ solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of electric charge will be

1. 44.8 L

2. 22.4 L

3. 11.2 L

4. 5.6 L

Subtopic:  Faraday’s Law of Electrolysis |
 58%
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