Which one is an outer orbital complex?
1. [Ni(NH3)6]2+
2. [Mn(CN)6]4-
3. [Co(NH3)6]3+
4. [Fe(CN)6]4-
[Cr(H2O)6]Cl3 (At. no. of Cr = 24) has a magnetic moment of 3.83 BM. What is the correct distribution of 3d electrons in the chromium of the complex:
1. 3d1xy, 3d1yz, 3d1z2
2. 3d(x2-y2), 3d1z2, 3d1xz
3. 3dxy, 3d(x2-y2), 3d1yz
4. 3d1xy, 3d1yz, 3d1zx
The IUPAC name of [CoCl(NO2)(en)2]Cl is:
1. Chloronitro-bis(ethylenediamine)cobalt(III)chloride
2. Chloronitro-bis(ethylenediamine)cobalt(II)chloride
3. Chloro-bis(ethylenediamine)nitrocobalt(III)chloride
4. Bis-(ethylenediamine)chloronitrocobalt(III)chloride
The probable formula for prussian blue is :
1. Fe3[Fe(CN)6]2
2. Fe2[Fe(CN)6]3
3. Fe4[Fe(CN)6]3
4. Fe3[Fe(CN)6]4
The IUPAC name of [Pt(NH3)4NO2Cl]SO4 is :
1. Chloronitroplatinum(IV)sulphate
2. Tetraamminechloridonitrito-Nplatinum(IV)sulphate
3. Chloronitrotetraammineplatinum(IV)sulphate
4. Platinum(IV)tetraamminenitrochloro sulphate
Mixture of X=0.02mole of [Co(NH3)5SO4]Br and 0.02 mole of [Co(NH3)5Br]SO4 was prepared in 2 litre of solution.
1 litre mixture X+excess AgNO3Y
1 Litre mixture X +excess BaCl2Z
No. of moles of Y and Z are :
1. 0.01,0.01
2. 0.02, 0.01
3. 0.01,0.02
4. 0.02,0.02
The compound that will exhibit maximum ionic conductivity in aqueous solution is:
1. K4[Fe(CN)6]
2. [Co(NH3)6]Cl3
3. [Cu(NH3)4]Cl2
4. [Ni(CO)4]
Which order is correct in spectrochemical series of ligands?
1. Cl-<F-<[C2O4]2-<NO2-<CN-
2. CN-<[C2O4)2-<Cl->NO2-<F-
3. [C2O4)2-<F-<Cl->NO2-<CN-
4. F-<Cl-<NO2-<CN-<[C2O4]2-
A solution of CuCl in NH4OH is used to measure the amount of gas by simply measuring change in volume. The gas is
1. CO2
2. H2
3. CO
4. All of the above.
Among the following complexes(K,P),K3[Fe(CN)6(k),[Co(NH3)6Cl3(L),Na3[Co(oxalate)3](M),[Ni(H2O)6Cl2(N),K2[Pt(CN)4(O), and [Zn(H2O)6(NO3)2(P) the diamagnetic complexes are:
1. K,L,M,N
2. K,M,O,P
3. L,M,O,P
4. L,M,N,O