A certain metal salt solutions is electrolysed in series with a silver coulometer. The weights of silver and the metal deposited are 0.5094 g and 0.2653 g. Calculate the valency of the metal if its atomic weight is nearly that of silver. 

(1) 1                                                 

(2) 2

(3) 3                                                 

(4) 4

The temperature coefficient, of the emf is $\frac{d\epsilon }{dT}$= – 0.00065 volt. $de{g}^{-1}$ for the cell $Cd\left|CdC{l}_2\left(1m\right)\right| \left|\underset{\left(s\right)}{AgCl}\right|Ag at 25°C$. Calculate the entropy change $∆S_{298K, }$ for the cell reaction,$Cd + 2AgCl \to C{d}^{++} + 2C{l}^{⊝}+ 2Ag$

$\left(1\right) – 105.5 J{K}^{-1}$

$\left(2\right) – 150.2 J{K}^{-1}$

$\left(3\right) – 75.5 J{K}^{-1}$

$\left(4\right) – 125.5 J{K}^{-1}$

The reduction potential of a half-cell consisting of a Pt electrode immersed in $1.5 M F{e}^{2+}$and $0.015 M F{e}^{3+}$ solution at $25°C is \left(E_{\left(F{e}^{+3}, Fe+2\right)}^{°}=+0.770 v\right)$.

(1) 0.652 V                                                   

(2) 0.88 V

(3) 0.710 V                                                   

(4) 0.850 V

In a concentration cell, $Zn/Z{n}^{2+} (1.0 M) \left|\right| Z{n}^{2+} (0.15 M)/Zn$ as the cell discharges,

(1) reaction proceeds to the right

(2) the two solutions approach each other in concentration

(3) no reaction takes place

(4) water gets decomposed

In a half-cell containing $\left[T{l}^{3+}\right] = 0.1 M and [T{l}^{+} ] = 0.01 M,$ the cell potential is – 1.2496 V for the reaction $T{l}^{+}\to T{l}^{3+} + 2e^{-}$  The standard reduction potential of the $T{l}^{+} /T{l}^{3+}$ couple at $25°C$ is

(1) 1.44 V                                          

(2) 0.61 V

(3) 2.44 V                                          

(4) 1.22 V

Given cell: 

Pt(s)|H₂(g)(P = 1 atm)| CH₃COOH(0.1 M), HCl(0.1 M) || KCl(aq)|Hg₂Cl₂(s)|Hg

EMF of the cell is found to be 0.045 V at 298 K and the temperature coefficient is 3.4×10^-4 V K^-1. The cell entropy change of the following cell is : 

[Given K_a CH₃COOH = 10^-5  M]

1. 70.8 J K⁻¹ mol⁻¹                      

2. 65.2 J K⁻¹ mol⁻¹

3. 79.2 J K⁻¹ mol⁻¹                  

4. 83.5 J K⁻¹ mol⁻¹

A dilute solution of $H_2 S{O}_4$ was electrolysed by passing a current of 2 amp. The time required for formation of 0.5 mole of oxygen is

(1) 26.8 hours                                    

(2) 13.4 hours

(3) 6.7 hours                                      

(4) 28.6 hours

The standard reduction potentials for $M{n}^{3+}/M{n}^{2+}$ and $Mn{O}_2 /M{n}^{3+}$ couples in acid medium at $25°C$ are 1.50 V and 1.00 V respectively. The following reaction:

$2M{n}^{3+} + 2H_{2}O \to M{n}^{2+} + Mn{O}_2 + 4H^{+} is$

(1) reversible                                             

(2) non-spontaneous

(3) spontaneous                                         

(4) irreversible

In the following electrochemical cell, $M|M^{+} || X^{-}|X,$ the standard reduction potentials are $E{°}_{M+/M}= 0.52 V$ and $E{°}_{X/X^{-}} = 0.42 V at 25°C.$ Which one of the following statements is correct ?

$\left(1\right) M + X \to M^{+} + X^{-} is spon\tan eous$              

$\left(2\right) M^{+} + X^{-} \to M + X is spon\tan eous$

$\left(3\right) E_{cell} = 0.77 V$                                              

$\left(4\right) E_{cell}= – 0.77 V$

1If a 100 mL solution of 0.1M HBr is titrated using a very concentrated solution of NaOH, when the conductivity (specific conductance) of the solution at the equivalence point will 3e (assume volume change is negligible due to addition of NaOH). Calculate your answer in terms of ${10}^{-1}S{m}^{-1},$

$\left[Given {{\wedge }^{°}}_{\left(N{a}^{+}\right)}=8\times {10}^{-3}S{m}^{2}mo{l}^{-1} {{\wedge }^{°}}_{\left(B{r}^{-}\right)}=4\times {10}^{-3}S m^2 mo{l}^{-1}\right]$

(1) 6                               

(2) 12

(3) 15                             

(4) 24