Consider the nitration of benzene using mixed conc. H2SO4 and HNO3.
If a large amount of KHSO4 is added to the mixture, the rate of nitration will be:
1. | Slower | 2. | Unchanged |
3. | Doubled | 4. | Faster |
If the equilibrium constant for N2(g) + O2 (g) ⇄ 2NO(g) is K, the equilibrium constant for \(\frac{1}{2}\)N2(g) + \(\frac{1}{2}\)O2(g) ⇄ NO(g) will be?
1.
2.
3. K
4.
Aqueous solution of which of the following compounds is the best conductor of electric current?
1. Acetic acid, \(\mathrm{C_{2} H_{4} O_{2}}\)
2. Hydrochloric acid, \(\mathrm{HCl}\)
3. Ammonia, \(\mathrm{N H_{3}}\)
4. Fructose, \(\mathrm{C_{6} H_{12} O_{6}}\)
The value of the equilibrium constant for a particular reaction is 1.6 × 1012. When the system is in equilibrium, it will include:
1. All reactants
2. Mostly reactants
3. Mostly products
4. Similar amounts of reactants and products
For the reversible reaction:
N2(g) + 3H2(g) \(\rightleftharpoons\) 2NH3(g) + heat
The equilibrium shifts in a forward direction:
1. by increasing the concentration of
2. by decreasing the pressure.
3. by decreasing the concentration of
4. by increasing pressure and decreasing temperature.
For a given exothermic reaction, Kp and Kp’ are the equilibrium constants at temperatures T1 and T2 respectively. Assuming that the heat of reaction is constant in temperatures range between T1 and T2, it is a readily observation that:
1.
2.
3.
4.
The strongest acid among the following compounds is:
1. | HClO3 | 2. | HClO4 |
3. | H2SO3 | 4. | H2SO4 |
Equimolar solutions of the following substances were prepared separately. Which one of these will record the highest pH value?
1. \(\mathrm{B a C l_{2}}\)
2. \(\mathrm{A l C l_{3}}\)
3. \(\mathrm{L i C l}\)
4. \(\mathrm{B e C l_{2}}\)
A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8×10–5, then what is the pH of this solution?
(log 1.8 = 0.25; log 0.67 = –0.176)
1. 9.43
2. 11.72
3. 8.73
4. 9.08