Q. No.
Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively:
| 1. | +3, +5, +4 | 2. | +5, +3, +4 |
| 3. | +5, +4, +3 | 4. | +3, +4, +5 |
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:
| 1. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction |
| 2. | In NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions |
| 3. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions |
| 4. | In NH3 the atomic dipole and the bond dipole is in opposite directions whereas in NF3 these are in the same directions |
The correct thermal stability order for \(\mathrm{{H}_2 {E}},\) \(\mathrm{{ E}= {O}, {S}, {Se}, {Te}} \text { and } \mathrm{Po}\) among the following is:
1. \(\mathrm{{H}_2 {Se}<{H}_2 {Te}<{H}_2 {Po}<{H}_2 {O}<{H}_2 S}\)
2. \(\mathrm{{H}_2 {~S}<{H}_2 {O}<{H}_2 {Se}<{H}_2 {Te}<{H}_2 {Po}}\)
3. \(\mathrm{{H}_2 {O}<{H}_2 {~S}<{H}_2 {Se}<{H}_2 {Te}<{H}_2 {PO}}\)
4. \(\mathrm{{H}_2 {Po}<{H}_2 {Te}<{H}_2 {Se}<{H}_2 {~S}<{H}_2 {O}}\)
Match the name of process given in Column I with the name of compound given in Column II and mark the correct option.
| Column I | Column II | ||
| (a) | Pure nitrogen | (i) | Chlorine |
| (b) | Haber process | (ii) | Sulphuric acid |
| (c) | Contact process | (iii) | Ammonia |
| (d) | Deacon's process | (iv) | Sodium azide or Barium azide |
| (a) | (b) | (c) | (d) | |
| 1. | (iv) | (iii) | (ii) | (i) |
| 2. | (i) | (ii) | (iii) | (iv) |
| 3. | (ii) | (iv) | (i) | (iii) |
| 4. | (iii) | (iv) | (ii) | (i) |
False statement regarding PCl5 is:
| 1. | PCl5 molecule is non-reactive. |
| 2. | Three equatorial P-Cl bonds make an angle of 120° with each other. |
| 3. | Two axial P-Cl bonds make an angle of 180° with each other. |
| 4. | Axial P-Cl bonds are longer than equatorial P-Cl bonds. |
The incorrect statement regarding oxoacids of phosphorus is:
| 1. | Orthophosphoric acid is used in the manufacture of triple superphosphate. |
| 2. | Hypophosphorous acid is a diprotic acid. |
| 3. | All oxoacids contain tetrahedral four coordinated phosphorus. |
| 4. | All oxoacids contain at least one P=O unit and one P-OH group. |
Which of the following compounds does not release oxygen when heated?
1. Zn(ClO3)2
2. K2Cr2O7
3. (NH4)2Cr2O7
4. KClO3
The acidity of diprotic acids in aqueous solution increases in the order:
1. H2S < H2Se < H2Te
2. H2Se < H2S < H2Te
3. H2Te < H2S < H2Se
4. H2Se < H2Te < H2S
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