The following equilibrium constants are given:
N2 + 3H2 ⇌ 2NH3; K1
N2 + O2 ⇌ 2NO; K2
H2 + 1/2O2 ⇌ H2O; K3
The equilibrium constant for the oxidation of NH3 by oxygen to give NO is:
1.
2.
3.
4.
Which one of the following orders correctly represents the increasing acid strengths of the given acids?
1.
2.
3.
4.
The following pair constitutes a buffer is:
1.
2.
3.
4.
Which composition will make the basic buffer?
1. | 100 mL of 0.1 M HCl+100 mL of 0.1 M NaOH |
2. | 50 mL of 0.1 M NaOH+25 mL of 0.1 M CH3COOH |
3. | 100 mL of 0.1 M CH3COOH+100 mL of 0.1 M NaOH |
4. | 100 mL of 0.1 M HCl+200 mL of 0.1 M NH4OH |
pH of a saturated solution of is 9. The solubility product of is:
1.
2.
3.
4.
1. H3O+ and H2F+, respectively.
2. OH– and H2F+, respectively.
3. H3O+ and F–, respectively.
4. OH– and F–, respectively.
A weak acid, HA, has a Ka of 1.00×10-5. If 0.100 mole of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to:
1. 99.0%
2. 1%
3. 99.9%
4. 0.100%
The pOH of a solution at 25 °C that contains 1×10-10 M of hydronium ions is:
1. | 7.00 | 2. | 4.00 |
3. | 9.00 | 4. | 1.00 |
The value of KP1 and Kp2 for the reactions
are in the ratio of 9 : 1. If the degree of dissociation of X and A is equal, then the total pressure at equilibrium(i) and (ii) are in the ratio:
1. 3 : 1
2. 1 : 9
3. 36 : 1
4. 1 : 1
The dissociation equilibrium of a gas AB2 can be represented as
The degree of dissociation is ‘x’ and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant KP and total pressure p is:
1. (2KP/p)
2. (2Kp /p)1/3
3. (2KP/p)1/2
4. (KP/P)