The bond energy of H—H and Cl-Cl is 430 kJ mol^-1 and 240 kJ mol^-1 respectively
and ΔH_f for HCl is -90 kJ mol^-1. The bond enthalpy of HCl is:

1. 290 $kJ$ $mo{l}^{-1}$

2. 380 $kJ$ $mo{l}^{-1}$

3. 425 $kJ$ $mo{l}^{-1}$

4. 245 $kJ$ $mo{l}^{-1}$

The enthalpy and entropy change for the reaction: Br₂ (l) + Cl₂ (g) →2BrCl(g), are 30kJ mol^-1 and 105 JK^-1 mol^-1 respectively. The temperature at which the reaction will be in equilibrium is: 

1. 285.7 K

2. 273 K

3. 450 K

4. 300 K

The enthalpy of combustion of H₂, cyclohexene (C₆H₁₀) and cyclohexane (C₆H₁₂) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:

1. -121 kJ per mol

2. +121 kJ per mol

3. +242 kJ per mol

4. -242 kJ per mol

Under the isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is:
[Given that 1 L bar = 100 J]

1. 30 J

2. –30 J

3. 5 kJ

4. 25 J

A process among the following shows decrease in entropy is :

1. \(2 \text H \left(g\right)\rightarrow\text H_{2} \left(g\right)\)

2. Evaporation of water

3. Expansion of a gas at a constant temperature

4. Sublimation of solid to gas

Consider the following reactions: 

Enthalpy of formation of H₂O(l) is :

1. $-x_3$ $kJ$ $mo{l}^{-1}$

2. $-x_4$ $kJ$ $mo{l}^{-1}$

3. $-x_1$ $kJ$ $mo{l}^{-1}$

4. $-x_2$ $kJ$ $mo{l}^{-1}$

The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK^-1, respectively.
C_(graphite) + CO₂(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K