For a given reaction, H =35.5 kJ mol-1 and S = 83.6JK-1 mol-1. The reaction is spontaneous at:
(Assume that H and S do not vary with temperature)

1. T < 425 K 2. T > 425 K
3. All temperatures 4. T > 298 K
Subtopic:  Gibbs Energy Change |
 73%
From NCERT
NEET - 2017
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A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy U of the gas in joules will be

(1) 1136.25 J

(2) - 500 J

(3) - 505 J

(4) + 515 J

Subtopic:  First Law of Thermodynamics |
 64%
From NCERT
NEET - 2017
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For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at:
(Assume that ∆H and ∆S  do not vary with temperature)
1. T > 425K
2. All temperatures
3. T > 298K
4. T < 425K

Subtopic:  Gibbs Energy Change |
 75%
From NCERT
NEET - 2017
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A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50 L to a final volume of 4.50L. The change in internal energy U of the gas in joules will be:
1. –500J
2. –505J
3. –506J
4. –508J

Subtopic:  First Law of Thermodynamics |
From NCERT
NEET - 2017
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The correct thermodynamic conditions for a spontaneous reaction at all temperatures is:
1. H > 0 and S< 0
2. H < 0 and S> 0
3. H < 0 and S< 0
4. H > 0 and S = 0
Subtopic:  Gibbs Energy Change |
 83%
From NCERT
NEET - 2016
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The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat changed upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ

Subtopic:  Thermochemistry |
 73%
From NCERT
NEET - 2015
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The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K

Subtopic:  Gibbs Energy Change |
 78%
From NCERT
NEET - 2015
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Given the Gibbs free energy change, \(\Delta \text G^\circ=+63.3~\text{kJ},\) for the following reaction, 
\(\mathrm{Ag_2 CO_3 (g) \rightarrow 2Ag^+ (aq) + CO^{2-}_3 (aq)}\)
\(\mathrm{K_{sp}}\) of \(\mathrm {Ag_2CO_3 (s) }\) in water at 25º C is (R = 8.314 JK–1 mol–1)
1. \(3.2 \times 10^{26}\)
2. \(8.0 \times 10^{-12}\)
3. \(2.9 \times 10^{-3}\)
4. \(7.9 \times 10^{-2}\)
Subtopic:  Gibbs Energy Change |
 60%
From NCERT
AIPMT - 2014
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Which of the following statements is correct for the spontaneous adsorption of a gas?

1. ∆ S is negative and therefore,  ∆ H should be highly positive
2. ∆ S is negative and therefore,  ∆ H should be highly negative
3. ∆ S is positive and therefore,  ∆ H should be negative
4. -∆ S is positive and therefore,  ∆ H should also be highly positive

Subtopic:  Spontaneity & Entropy |
 56%
From NCERT
AIPMT - 2014
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Given the reaction: 
X2O4(l) → 2XO2(g) 
ΔU = 2.1 kcal, ΔS = 20 cal K–1 at 300 K 
The value of ΔG is:
1. 2.7 kcal
2. –2.7 kcal
3. 9.3 kcal
4. –9.3 kcal

Subtopic:  Gibbs Energy Change |
 78%
From NCERT
AIPMT - 2014
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