For a given reaction, H =35.5 kJ mol-1 and S = 83.6JK-1 mol-1. The reaction is spontaneous at:
(Assume that H and S do not vary with temperature)
1. | T < 425 K | 2. | T > 425 K |
3. | All temperatures | 4. | T > 298 K |
A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy U of the gas in joules will be
(1) 1136.25 J
(2) - 500 J
(3) - 505 J
(4) + 515 J
For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at:
(Assume that ∆H and ∆S do not vary with temperature)
1. T > 425K
2. All temperatures
3. T > 298K
4. T < 425K
A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5atm from an initial volume of 2.50 L to a final volume of 4.50L. The change in internal energy U of the gas in joules will be:
1. –500J
2. –505J
3. –506J
4. –508J
The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat changed upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ
The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K
Which of the following statements is correct for the spontaneous adsorption of a gas?
1. | ∆ S is negative and therefore, ∆ H should be highly positive |
2. | ∆ S is negative and therefore, ∆ H should be highly negative |
3. | ∆ S is positive and therefore, ∆ H should be negative |
4. | -∆ S is positive and therefore, ∆ H should also be highly positive |
Given the reaction:
X2O4(l) → 2XO2(g)
ΔU = 2.1 kcal, ΔS = 20 cal K–1 at 300 K
The value of ΔG is:
1. 2.7 kcal
2. –2.7 kcal
3. 9.3 kcal
4. –9.3 kcal