If the molar concentration of SnCl4 is 1.5 × 10-3 mol L–1, the concentration of chloride ions will be:

1. 3.0 x 10-3 2. 6.0 x 10-3
3. 0.3 x 10-3 4. 0.6 x 10-6
Subtopic:  Introduction To Equilibrium |
 73%
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Which of the following is an example of a reversible reaction?

1. \(\small{KNO_3(aq) + NaCl(aq) \rightleftharpoons KCl(aq) + NaNO_3(aq)} \)
2. \(\small{2Na(s) + H_2O(l) \rightleftharpoons 2NaOH(aq) + H_2(g)} \)
3. \(\small{AgNO_3(aq) + NaCl(aq) \rightleftharpoons AgCl(s) + NaNO_3(aq)} \)
4. \(\small{Pb{(NO_3)}_2(aq) + 2NaI(aq) \rightleftharpoons PbI_2(s) + 2NaNO_3(aq)} \)
Subtopic:  Introduction To Equilibrium |
 59%
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An incorrect statement about equilibrium among the following is:

1. Equilibrium is possible only in a closed system at a constant temperature.
2. All measurable properties of the system remain constant.
3. All the physical processes stop at equilibrium.
4. The opposing processes occur at the same rate and there is a dynamic but stable condition.
Subtopic:  Introduction To Equilibrium |
 74%
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In the reaction, N2O4(g)  2NO2(g), α is that part of N2O4 which dissociates. The number of moles at equilibrium will be:

1. 1-α2

2. 3α

3. α

4. 1+α

Subtopic:  Introduction To Equilibrium |
 77%
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In the reaction A(g) + 2B(g) ⇌ 2C(g) + D(g), the initial concentration of B is twice that of A and, at equilibrium, the concentrations of A and D are equal. The value of the equilibrium constant will be:

1. 4 2. 16
3. 2 4. 1
Subtopic:  Introduction To Equilibrium |
 67%
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HI was heated in a sealed tube at 440°C till the equilibrium was reached. At this point, HI was found to be 22 % decomposed. The equilibrium constant for this dissociation is :

1. 0.28 2. 0.08
3. 0.02 4. 1.99
Subtopic:  Introduction To Equilibrium |
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Consider the following reaction taking place in 1L capacity container at 300 K.
\(\mathrm{A +B \rightleftharpoons C+D }\)
If one mole each of A and B are present initially and at equilibrium 0.7 mol of C is formed, then the equilibrium constant \((K_c) \) for the reaction is:

1. 9.7  2. 1.2 
3. 6.2  4. 5.4 
Subtopic:  Introduction To Equilibrium |
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Kp for the following reaction is 3.0 at 1000 K.
\(\mathrm{CO_{2}(g)\,+\,C(s)\rightarrow \,2CO(g)}\)
The value of Kfor the reaction at the same temperature is: 
(Given - R = 0.083 L bar K–1 mol–1)
1. 0.36 2. 3.6 × 10–2
3. 3.6 × 10–3 4. 3.6
Subtopic:  Introduction To Equilibrium |
 79%
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Ka1, Ka2 and Ka3 are the respective ionisation constants for the following reactions.
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-}\)
\(\mathrm{HS}^{-} \rightleftharpoons \mathrm{H}^{+}+\mathrm{S}^{2-}\)
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{S}^{2-}\)
The correct relationship between Ka1, Ka2 and Ka3 is:
1. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} \times \mathrm{K}_{\mathrm{a}_2} \)
2. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1}+\mathrm{K}_{\mathrm{a}_2} \)
3. \(K_{a_3}=K_{a_1}-K_{a_2} \)
4. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} / \mathrm{K}_{\mathrm{a}_2}\)

Subtopic:  Introduction To Equilibrium |
 81%
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Reaction quotient for the reaction, N2(g)+3H2(g)2NH3(g) is given by , Q = [NH3]2[N2][H2]3 .The reaction will proceed from right to left if Kc value is:

1. Q<Kc  2. Q=0
3. Q>Kc  4. Q=Kc 
Subtopic:  Introduction To Equilibrium |
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