Q. No.The correct order of atomic radii of the group 13 elements is-
1. B < Al < In < Ga < Tl
2. B < Al < Ga < In < Tl
3. B < Ga < Al < Tl < In
4. B < Ga < Al < In < Tl
| List-I (Compounds) |
List-II (Molecular formula) |
||
| (a) | Borax | (i) | NaBO2+B2O3 |
| (b) | Kernite | (ii) | Na2B4O7.4H2O |
| (c) | Orthoboric acid | (iii) | H3BO3 |
| (d) | Borax bead | (iv) | Na2B4O7.10H2O |
Choose the correct answer from the options given below :
| (a) | (b) | (c) | (d) | |
| 1. | (iv) | (ii) | (iii) | (i) |
| 2. | (ii) | (iv) | (iii) | (i) |
| 3. | (iii) | (i) | (iv) | (ii) |
| 4. | (i) | (iii) | (iv) | (ii) |
The element among the following that does not show inert pair effect is-
| 1. | Al | 2. | Sn |
| 3. | Pb | 4. | Thallium |
Ionization enthalpy () for the elements of Group 13 follows the order.
| 1. | B > Al > Ga > In > Tl | 2. | B < Al < Ga < In < Tl |
| 3. | B < Al > Ga < In > Tl | 4. | B > Al < Ga > In < Tl |
Assertion: Boron always forms a covalent bond.
Reason: Boron has a diagonal relationship with silicon.
1. Both Assertion & Reason are true and the reason is the correct explanation of the assertion.
2. Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.
3. Assertion is a true statement but Reason is false.
4. Both Assertion and Reason are false statements.
The correct explanation for the lower atomic radius of Ga as compared to Al is -
1. Poor shielding effect of the 2d-electrons
2. Poor shielding effect of the 3d-electrons
3. Poor shielding effect of the 3p-electrons
4. Poor shielding effect of the 2s-electrons
Which of the following is the correct statement?
1. Ga+ is more stable than ln+.
2. Al+ is more stable than ln+.
3. Ga+ is more stable than Al+.
4. Al+ is more stable than Ga+.
1. \(\mathrm{TlI > TlI_3}\)
2. \(\mathrm{TlCl_3 > TlCl}\)
3. \(\mathrm{InI_3 > InI }\)
4. \(\mathrm{AlCl > AlCl_3 }\)
\(\begin{aligned} & \mathrm{Al}^+ / \mathrm{Al}=+0.55 \mathrm{~V} \text { and } \mathrm{Tl}^{+} / \mathrm{Tl}=-0.34 \mathrm{~V} \\ & \mathrm{Al}^{3+} / \mathrm{Al}=-1.66 \mathrm{~V} \text { and } \mathrm{Tl}^{3+} / \mathrm{Tl}=+1.26 \mathrm{~V} \end{aligned} \)
The incorrect statement among the following is:
1. Al is more electropositive than TI.
2. Tl3+ is a good reducing agent than Tl1+.
3. Al+ is unstable in solution.
4. Tl can be easily oxidized to Tl+ as compared to Tl3+.
Aluminium becomes passive in nitric acid because it-
1. Is a noble metal
2. Forms a thin film of oxide
3. Has a positive reduction potential
4. None of the above
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