Based on the graph below, the average rate of reaction will be: 

1.  \(\frac{[R_{2}]-[R_{1}]}{t_{2}-t_{1}}\)
2.  \(-(\frac{[R_{2}]-[R_{1}]}{t_{2}-t_{1}})\)
3.  \(\frac{[R_{2}]}{t_{2}}\)
4.  \(-(\frac{[R_{1}]-[R_{2}]}{t_{2}-t_{1}})\)

Subtopic:  Definition, Rate Constant, Rate Law |
 72%
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Match the items in Column I with Column II:

Column I Column II
A. Diamond to graphite conversion 1. Short interval of time
B. Instantaneous rate 2. Ordinarily rate of conversion is imperceptible
C. Average rate 3. Long duration of time

Codes:

A B C
1. 2 1 3
2. 1 2 3
3. 3 2 1
4. 1 3 2
Subtopic:  Definition, Rate Constant, Rate Law |
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Consider the following graph:
      

The instantaneous rate of reaction at t = 600 sec will be:

1. - 4.75 ×10-4 mol L-1s-1
2. 5.75×10-5 mol L-1s-1
3.  6.75×10-6 mol L-1s-1
4. -6.75×10-6 mol L-1s-1

Subtopic:  Definition, Rate Constant, Rate Law |
 54%
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In the following reaction: xA →  yB

log-d[A]d= log d[B]dt + 0.3 

where the -ve sign indicates the rate of disappearance of the reactant. Then, x : y equals:

1. 1:2 2. 2:1
3. 3:1 4. 3:10
Subtopic:  Definition, Rate Constant, Rate Law |
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A gaseous reaction A2(g) → B(g) + 12C(g) shows increase in pressure from 100 mm to 120 mm in 5 minutes. The rate of disappearance of Awill be : 

1. 4 mm min-1 2. 8 mm min-1
3. 16 mm min-1 4. 2 mm min-1
Subtopic:  Definition, Rate Constant, Rate Law |
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During the formation of ammonia by Haber's process N+ 3H2 → 2NH3, the rate of appearance of NH3 was measured as 2.5 x 10-4 mol L-1 s-1. The rate of disappearance of H2 will be: 

1. 2.5 x 10-4 mol L-1 s-1

2. 1.25 x 10-4 mol L-1 s-1

3. 3.75 x 10-4 mol L-1 s-1

4. 15.00 x 10-4 mol L-1 s-1

Subtopic:  Definition, Rate Constant, Rate Law |
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For the reaction,

N2O5(g) → 2NO2(g) + \(\frac{1}{2}\)O2(g)

the value of the rate of disappearance of N2O5 is given as 6.25 × 10-3 mol L-1s-1. The rate of formation of NO2 and O2 is given respectively as:

1. 6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1

2. 1.25 x 10-2 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1

3. 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1

4. 1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1

Subtopic:  Definition, Rate Constant, Rate Law |
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The following reaction was carried out at 300 K.

2SO2(g)  +  O2(g) →  2SO3(g)

The rate of formation of SO3 is related to the rate of disappearance of O2  by the following expression:

1. -O2t=+12SO3t                           

2. -O2t=SO3t

3. -O2t=-12SO3t                           

4. None of the above.

Subtopic:  Definition, Rate Constant, Rate Law |
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For the reaction, \(\mathrm{N}_2+3 \mathrm{H}_2 \rightarrow 2 \mathrm{NH}_3,\) if, \(\frac{d[NH_{3}]}{dt} \ = \ 2\times 10^{-4} \ mol \ L^{-1} \ s^{-1}\), the value of  \(\frac{-d[H_{2}]}{dt}\) would be:

1. \(3 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \) 2. \(4 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \)
3. \(6 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1} \) 4. \(1 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 85%
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AIPMT - 2009
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For the reaction, \(2 A+B \rightarrow 3 C+D\)

An incorrect expression for the rate of reaction is:

1. \(-\frac{d[C]}{3} d t \) 2. \(-\frac{d[B]}{d t} \)
3. \(\frac{d[D]}{d t} \) 4. \(-\frac{d[A]}{2 d t}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
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