Which of the following can be used as the halide component for Friedel-Crafts reaction?

(1) Chlorobenzene

(2) Bromobenzene

(3) Chloroethene

(4) Isopropyl chloride

In the given reaction

the product P is:

1.		2.
3.		4.

Consider the reaction 

CH₃CH₂CH₂Br + NaCN $\to$CH₃CH₂CH₂CN + NaBr

This reaction will be the fastest in

1. ethanol

2. methanol

3. N,N'-dimethylformamide (DMF)

4. water

The compound that will react most readily with gaseous bromine has the formula ?
(1) C₃H₆

(2) C₂H₂

(3) C₄H₁₀

(4) C₂H₄

The reaction of C₆H₅CH=CHCH₃ with HBr produces


 

Which one is the most reactive toward S_N1 reaction?

1. C₆H₅CH(C₆H₅)Br

2. C₆H₅CH(CH₃)Br

3. C₆H₅C(CH₃)(C₆H₅)Br

4. C₆H₅CH₂Br

In S_N2 substitution reaction of the type

$R - \mathrm{Br} + {\mathrm{Cl}}^{-} \stackrel{\mathrm{DMF}}{\to }R - \mathrm{Cl} + {\mathrm{Br}}^{-},$

Which one of the following has the highest relative rate ?

(1) ${\mathrm{CH}}_3-{\mathrm{CH}}_2-{\mathrm{CH}}_2\mathrm{Br}$

(2) ${\mathrm{CH}}_3-\underset{\underset{{\mathrm{CH}}_3}{|}}{\mathrm{C}}\mathrm{H}-{\mathrm{CH}}_2\mathrm{Br}$

(3) ${\mathrm{CH}}_3-\underset{\underset{{\mathrm{CH}}_3}{|}}{\overset{\underset{|}{{\mathrm{CH}}_3}}{\mathrm{C}}}-{\mathrm{CH}}_2\mathrm{Br}$

(4) ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Br}$

Which compound in each of the following pairs will react faster in an \(S_N 2\) reaction with the −OH group?

 (i) \(\mathrm{CH}_3 \mathrm{Br}\) or \(\mathrm{CH}_3 \mathrm{I}\)
(ii) \(\left(\mathrm{CH}_3\right)_3 \mathrm{CCl}\) or \(\mathrm{CH}_3 \mathrm{Cl}\)

Mark the correct option:
1.  (i) \(\mathrm{CH}_3 \mathrm{Br}\) and (ii) \(\left(\mathrm{CH}_3\right)_3 \mathrm{CCl}\)
2.  (i) \(\mathrm{CH}_3 \mathrm{I}\) and (ii) \(\mathrm{CH}_3 \mathrm{Cl}\)
3.  (i) \(\mathrm{CH}_3 \mathrm{Br}\) and (ii) \(\mathrm{CH}_3 \mathrm{Cl}\)
4.  (i)\(\mathrm{CH}_3 \mathrm{I}\)and (ii) \(\left(\mathrm{CH}_3\right)_3 \mathrm{CCl}\)

A few reactions are given below:

i.	\(\small{\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Br}+\mathrm{KOH} \rightarrow \mathrm{CH}_3 \mathrm{CH}=\mathrm{CH}_2+\mathrm{KBr}+\mathrm{H}_2 \mathrm{O}}\)
ii.
iii.

Which of the following biphenyls is optically active?

1.
2.
3.
4.