The number of ions produced in water by the dissolution of the complex having the empirical formula [Co(NH₃)₄Cl₂]CI is: 

1. 1

2. 2

3. 4

4. 3

Spin-only magnetic moments of [Fe(NH₃)₆]³⁺ and [FeF₆]^3-  in BM are, respectively :

In an aqueous solution, ${\left[\mathrm{Co}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]}^{2+}$ (X) reacts with molecular oxygen in the presence of excess liquor $N{H}_3$ to give a new complex Y. The number of unpaired electrons in X and Y are, respectively

1. 3, 1

2. 3, 0

3. 3, 3

4. 7, 0 

The energies of ${\mathrm{d}}_{\mathrm{xy}} \mathrm{and} {{\mathrm{d}}_{\mathrm{z}}}^2$ orbitals in octahedral and tetrahedral transition metal complexes are such that

1. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

2. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in both tetrahedral and octahedral complexes

3. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes

4. $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) < \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$  in tetrahedral but $\mathrm{E}\left({\mathrm{d}}_{\mathrm{xy}}\right) > \mathrm{E}\left({\mathrm{d}}_{{\mathrm{z}}^2}\right)$ in octahedral complexes   

The number of geometrical isomers of [CrCl₂en(NH₃)₂] are:
[en-ethylenediamine]

The geometry and the number of the unpaired electron(s) of \([MnBr_{4}]^{2-}\), respectively, are:

The complex that can exhibit optical activity among the following is:

1. [CoCl₆]^3-

2. [Co(en)CI₄]^-

3. cis-[Co(en)₂Cl₂]⁺

4. trans-[Co(en)₂Cl₂]⁺ 

2.335 g of compound X (empirical formal CoH₁₂N₄Cl₃) upon treatment with excess AgNO₃ solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

The geometry and magnetic property of ${\left[{\mathrm{NiCl}}_4\right]}^{2-}$, respectively, are

1.  Tetrahedral, Paramagnetic

2.  Tetrahedral, Diamagnetic

3.  Square planar, Paramagnetic

4.  Square planar, Diamagnetic  

Among
(i) [Cr(en)₃]³⁺
(ii) trans-[Cr(en)₂Cl₂]⁺
(iii) cis-[Cr(en)₂Cl₂]⁺
(iv) [Co(NH₃)₄Cl₂]⁺
the optically active complexes are-

1. (i), (ii) and (iii)

2. (i) and (iii)

3. (ii) and (iii)

4. (ii) and (iv)