Which of the following statements is not correct for a nucleophile?

1.  Nucleophile is a lewis acid.
2.  Ammonia is a nucleophile.
3.  Nucleophiles attack low electron density sites.
4.  Nucleophiles are not electron-seeking.

Subtopic:  Nucleophile & Electrophile |
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The pair of electron in the given carbanion, CH3C≡C, is present in which orbitals?
1. sp3
2. sp2
3. sp
4. 2p

 

Subtopic:  Hybridisation | V.S.E.P.R & V.B.T |
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The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is
1. The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed conformation has no torsional strain
2. The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has torsional strain
3. The staggered conformation of ethane is more stable than eclipsed conformation, because staggered conformation has no torsional strain
4. The staggered conformation of ethane is less stable than eclipsed conformation, because staggered conformation has torsional strain

 

Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
 75%
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For the following reactions, 

(i) CH3CH2CH2Br + KOHCH3CH=CH2 + KBr + H2
 

(ii) 
 

(iii)  
Which of the following statements is correct?
1. (i) is elimination, reaction, (ii) is substitution and (iii) is addition reaction
2. (i) is elimination, (ii) and (iii) are substitution reactions
3. (i) is substitution, (ii) and (iii) are addition reactions
4. (i) and (ii) are elimination reactions and (iii) is addition reaction

 

Subtopic:  Chemical Properties |
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Which of the following molecules represents the order of hybridisation sp2,sp2,sp,sp from left to right atoms?
1. HCC-CH
2. CH2=CH-CCH
3. CH2=CH-CH=CH2
4. CH2-CH=CH-CH3

 

Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
 81%
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Which of the following carbocations is expected to be most stable?
1. 
2. 
3. 
4. 

 

Subtopic:  Electron Displacement Effects |
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The correct(s) order among the following concerning the –I effect of the substituents:
(R= alkyl)
a. -NH2<-OR<-F
b. -NR2<-OR<-F
c. -NH2>-OR>-F
d. -NR2>-OR>-F
1. Both b and d  2. Both a and c
3. Both a and b 4. Both d and a
Subtopic:  Electron Displacement Effects |
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Which among the given molecules can exhibit tautomerism? 

1.  III only

2.  Both I and III

3.  Both I and II

4.  Both II and III

Subtopic:  Structural Isomers |
 68%
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With respect to the conformers of ethane, which of the following statements is true?

1. Bond angle changes but bond length remains the same
2. Both bond angle and bond length change
3. Both bond angle and bond length remain the same
4. Bond angle remains the same but the bond length changes
Subtopic:  Conformational Isomers |
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The correct statement regarding electrophile is:

1. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from another electrophile.
2. Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a nucleophile.
3. Electrophile can be either neutral or positively charged species and can form a bond accepting a pair of electrons from a nucleophile.
4. Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a nucleophile

Subtopic:  Nucleophile & Electrophile |
 86%
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