Self condensation of two moles of ethyl acetate in presence of sodium ethoxide yields :
1. Ethyl butyrate
2. Acetoacetic ester
3. Methyl acetoacetate
4. Ethyl propionate
Nucleophilic addition reaction will be most favoured in-
1.
2.
3.
4.
A carbonyl compound reacts with hydrogen cyanide to form cyanohydrins which on hydrolysis forms a racemic mixture of α-hydroxy acid. The carbonyl compound is :
1. Acetaldehyde
2. Acetone
3. Diethyl ketone
4. Formaldehyde
In a set of reactions propanoic acid yielded a compound D.
The structure of D would be :
1.
2.
3.
4.
The product formed in aldol condensation is :
1. A beta-hydroxy acid
2. A beta-hydroxy aldehyde or a beta-hydroxy ketone
3. An alpha-hydroxy aldehyde or ketone.
4. An alpha, beta unsaturated ester
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Consider the following compounds :
(i) C6H5COCl
(ii)
(iii)
(iv)
The correct decreasing order of their reactivity towards hydrolysis is :
1. (ii)>(iv)>(iii)>(i)
2. (i)>(ii)>(iii)>(iv)
3. (iv)>(ii)>(i)>(iii)
4. (ii)>(iv)>(i)>(iii)
A strong base can abstract an - hydrogen from:
1. Alkene
2. Amine
3. Ketone
4. Alkane
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1. Acyl chloride > Acid anhydride > Ester > Amide
2. Ester > Acyl chloride > Amide >Acid anhydride
3. Acid anhydride > Amide > Ester > Acyl chloride
4. Acyl chloride > Ester > Acid anhydride > Amide
Acetophenone when reacted with a base, C2H5ONa, yields a stable compound which has the structure
1.
2.
3.
4.
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1. | 2. | ||
3. | 4. |
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