How many octahedral and tetrahedral holes are present per unit cell in a face centred cubic arrangement of atoms?
(1) 8,4
(2) 1.2
(3) 4.8
(4) 2.1
Choose the correct matching sequence from the possibilities given
(a) Crystal defect | (i) AB AB AB. . . . type crystal |
(b) hcp | (ii) Covalent crystal |
(c) CsCl | (iii) Frenkel |
(d) Diamond | (iv) Face centered in cube |
(e) NaCl | (v) Body centered in cube |
(a) | (b) | (c) | (d) | (e) | |
(1) | (iii) | (i) | (ii) | (v) | (iv) |
(2) | (iii) | (i) | (v) | (ii) | (iv) |
(3) | (iii) | (v) | (i) | (ii) | (iv) |
(4) | (v) | (iii) | (iv) | (ii) | (i) |
An element (atomic mass = 100 g mole) having BCC structure has unit cell edge 400 . The density of the element is (number of atom bcc(z)=2)
1. 2.144g/cm3
2. 5.2g/cm3
3. 7.289g/cm3
4. 10.376g/cm3
The appearance of color in solid alkali metal halides is generally due to:-
1. Frankel Defect
2. Interstitial Defect
3. F-Centres
4. Schottky Defect
AB crystallizers in a body-centred cubic lattice with edge length a equal to 387 pm. The distance between two oppositely charged ions in the lattice is
1. 250 pm
2. 200 pm
3. 300 pm
4. 335 pm
In a face centred cubic lattice, atom A occupies the corner positions and atom B occupies the face centre positions. If one atom of B is missing from one of the face centred points, the formula of the compound is -
1. AB2
2. A2B3
3. A2B5
4. A2B
Packing fraction of simple cubic crystal lattice is
1. 38%
2. 74%
3. 68%
4. 52.4%
Silver metal crystallises in a cubic closest – packed arrangement with the edge of the unit cell having a length a = 407 pm. What is the radius of silver atom.
(1) 143.9 pm
(2) 15.6 pm
(3) 11.59 pm
(4) 13.61 pm
Given that the length of the side of a unit cell of lithium is 351 pm, its atomic radius will be -
[Li forms Bcc crystals]
1. 153.69 pm
2. 62.71 pm
3. 151.98 pm
4. 54.61 pm
Lithium borohydride crystallises in an orthorhombic system with 4 molecules per unit cell. The unit cell dimensions are : a = 6.81Å, b= 4.43Å, c=7.17Å. If the molar mass of is 21.76 g mol–1. The density of the crystal is –
(1) 0.668 g cm–3
(2) 0.585 g cm2
(3) 1.23 g cm–3
(4) None