At 298 K, 500cm³ H₂O dissolved 15.30 cm³ CH₄(STP) under a partial pressure of methane of one atm. If Henery's law holds, what pressure is required to cause 0.001 mole methane to dissolve in 300cm³ water ?

(1) 0.286 atm

(2) 2.486 atm

(3) 1.286 atm

(4) 3.111 atm

Which of the following colligative properties is associated with the concentration term 'molarity'?

(1) Lowering of vap.pressure

(2) Osmotic pressure

(3) Depression in freezing point

(4) Elevation in boiling point

The vapoure pressure of a dilute aqueous solution of glucose is 750mm of mercury at 373K. The mole fraction of solute in the solution is-

(1) 1/10

(2) 1/76

(3) 1/7.6

(4) 1/35

A pair of  isotonic solutions, among the following, is (assuming temperature to be the same) :

1. 0.1 (M) urea and 0.1 (M) NaCl

2. 0.1 (M) urea and 0.2 (M) MgCl₂

3. 0.1 (M) NaCl and 0.1 (M) Na₂SO₄

4. 0.1 (M) Ca(NO₃)₂ and 0.1 (M) Na₂SO₄

A solution having osmotic pressure nearer to that of an equimolar solution of K₄[Fe(CN)₆] is-

1. Na₂SO₄

2. BaCl₂

3. Al₂(SO₄)₃

4. C₁₂H₂₂O₁₁ 

A two phase system consisting of a liquid dispersed in another liquid is known as-

(A) Foam 

(B) Suspension

(C) Emulsion

(D) Mist

The partial pressure of ethane over a saturated solution containing 3.56 X 10^-2 g of ethane is 3 bar. If the solution contains 9.00 X 10^-2 g of ethane, then what will be the partial pressure of the gas?

1. 0.76 bar

2. 0.16 bar

3. 7.82 bar

4. 3.12 bar

An aqueous solution of hydrochloric acid -

1. Obeys Raoult's law

2. Shows negative deviations from Raoult's law

3. Shows positive deviations from Raoult's law

4. Obeys Henry's law at all compositions

Osmotic pressure of equimolar solution of BaCl₂, NaCl and glucose will be in the order -

(1) BaCl₂ > NaCl > glucose

(2) glucose > NaCI > BaCl₂

(3) NaCl > BaCl₂ >glucose

(4) NaCl> glucose > BaCl₂

The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol individually. The mixture shows:

1. No deviation from Raoult's law

2. Positive deviation from Raoult's law

3. Negative deviation from Raoult's law

4. That the solution is unsaturated