Standard Reduction electrode potential of three metals X, Y and Z are -1.2V, + 0.5V and -3V respectively. The reducing power of these metals will be 

(1) Y>X>Z

(2) Z>X>Y

(3) X>Y>Z

(4) Y>Z>X

Subtopic:  Electrochemical Series |
 88%
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How many columbs of electricity are consumed when 100 mA current is passed through a solution of AgNO3 for 30 minute during an electrolysis experiment?

(1) 108

(2) 18000

(3) 180

(4) 3000

Subtopic:  Faraday’s Law of Electrolysis |
 81%
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Standard reduction potentials at 25°C of Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are -3.05, -2.90, -2.71 and -2.37 V respectively. Which one of the following is the strongest oxidising agent ?

(1) Mg2+

(2) Ba2+

(3) Na+

(4) Li+

Subtopic:  Electrode & Electrode Potential |
 83%
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For the cell, Ti/Ti+(0.001M)||Cu2+(0.1M)|Cu, Ecello at

25 °C is 0.83 V. Ecell can be increased :

1. By increasing [Cu2+]

2. By increasing [Ti+]

3. By decreasing [Cu2+]

4. None of the above.

Subtopic:  Nernst Equation | Faraday’s Law of Electrolysis |
 72%
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A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI of pH = 10 and by passing hydrogen gas around the platinum wire at 1 atm pressure. The oxidation potential of electrode would be

1. 0.059 V

2. 0.59 V

3. 00.118 V

4. 1.18 V

Subtopic:  Electrode & Electrode Potential |
 77%
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The atomic mass of Al is 27. When a current of 5 faraday is passed through a solution of Al3+ ions, the mass of Al deposited is:

(1) 27g

(2) 36g

(3) 45g

(4) 9g

Subtopic:  Faraday’s Law of Electrolysis |
 91%
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On the basis of the information available from the reaction.

43Al + O2           23Al2O3, G =-827kJ mol-1 

of O2, the minimum EMF required to carry out the electrolysis of Al2O3 is :(F=96500 C mol-1

(1) 2.14 V

(2) 4.28 V

(3) 6.42 V

(4) 8.56 V

Subtopic:  Faraday’s Law of Electrolysis |
 62%
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For the reduction of silver ions with copper metal, the standard cell potential was found to be + 0.46 V at 25ºC. The value of standard Gibbs energy, Gwill be:
(F = 96500 Cmol-1)

1. -89.0 KJ

2. 89.0 J

3. -44.5 KJ

4. -98.0 KJ

Subtopic:  Relation between Emf, G, Kc & pH |
 70%
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A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively:

(1) H2, O2

(2) O2, H2

(3) O2, Na

(4) O2, SO2

Subtopic:  Electrolytic & Electrochemical Cell |
 74%
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If a salt bridge is removed from the two half cells, the voltage:

(1) drops to zero

(2) does not change

(3) increases gradually

(4) increases rapidly

Subtopic:  Batteries & Salt Bridge |
 77%
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