For the reaction 2NO₂ + F₂ → 2NO₂F, following

mechanism has been provided,

 NO₂ + F₂   $\stackrel{slow}{\to }$  NO₂F+F

NO₂ + F   $\stackrel{fast}{\to }$ NO₂F

Thus, rate expression of the above

reaction can be written as:

(a) r = K[NO₂]²[F₂]

(b) r = K[NO₂ ][F₂]

(c) r = K[NO₂]

(d) r = K[F₂]

For the reaction:

[Cu(NH₃)₄]²⁺ + H₂O_{$\rightleftharpoons$}[Cu(NH₃)₃H₂O]²⁺ + NH₃

the net rate of reaction at any time is given by, net rate =

2.0x10^-4 [Cu(NH₃)₄]²⁺[H₂O] - 3.0x10⁵ [Cu(NH₃ )₃ H₂0]²⁺[NH₃]

Then correct statement is/are :

(a) rate constant for forward reaction = 2 x 10^-4

(b) rate constant for backward reaction = 3 x 10⁵

(c) equilibrium constant for the reaction = 6.6 x 10^-10

(d) all of the above

A reactant with initial concentration 1.386 mol litre^-1 showing first order change takes 40 minute to become half. If it shows zero order change taking 20 minute to becomes half under the similar conditions, the ratio, K₁/K₀ for first order and zero order kinetics will be:

(1) 0.5 mol^-1 litre

(2) 1.0 mol/litre

(3) 1.5 mol/litre

(4) 2.0 mol^-1 litre

In a first order reaction, the concentration of the reactant is decreased from 1.0 M to 0.25M in 20 minute. The rate constant of the reaction would be:

(1) 10min^-1

(2) 6.931 min^-1

(3) 0.6931 min^-1

(4) 0.06931 min^-1

The rate constant of a first order reaction is 4x10^-3 sec^-1. At a reactant concentration of 0.02 M, the rate of reaction would be:

(a) 8 x 10^-5 Msec^-1

(b) 4 x 10^-3 Msec^-1

(c) 2 x 10^-1 Msec^-1

(d) 4 x 10^-1 Msec^-1

If concentration of reactants is increased by 'X', the rate constant K becomes:

(a) e^K/X

(b) K/X

(c) K

(d) X/K

A graph plotted between log (t) 50% vs. log (a) concentration is a straight line. What conclusion can you draw from the given graph?

(a) n=1, t_1/2 = 1/K.a

(b) n=2, t_1/2 = 1/a

(c) n=1, t_1/2 = 0.693/K

(d) None of the above

The rate of a chemical reaction doubles for every 10°C rise of temperature. If the temperature is raised by 50°C, the rate of the reaction increases by about :

(a) 10 times

(b) 24 times

(c) 32 times

(d) 64 times

Consider the reaction:

Cl₂(aq) + H₂S(aq) → S(s) +2H⁺(aq) +2Cl^-(aq)

The rate equation for this reaction is rate = k[Cl₂][H₂S] Which of these mechanisms is/are consistent with this rate equation?

A. Cl₂ + H₂S → H⁺ + Cl^- +Cl⁺ + HS^- (slow)

cl⁺ + HS^- → H⁺ +Cl^- + S (fast)

B. H₂S $\iff$ H⁺ + HS^- (fast equilibrium)

Cl₂ + HS^- → 2Cl^- + H⁺ + S (slow)

(1) A only

(2) B only

(3) Both A and B

(4) Neither A nor B