Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3, and CuSO4, respectively are connected in series.

A steady current of 1.5 amperes was passed through them until 1.45 g of silver was deposited at the cathode of cell B. The current flow time is-

1. 14 minutes

2. 25 minutes

3. 20 minutes

4. 11 minutes

Subtopic:  Faraday’s Law of Electrolysis |
 62%
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If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

1. 2.35 × 10-22
2. 2.25 × 1022
3. 1.34 × 1021
4. 3.16 × 1024

Subtopic:  Faraday’s Law of Electrolysis |
 81%
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What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr2O72-? Consider the reaction: Cr2O72- + 14H+ +6e-   2Cr+3 + 7H2O

1. 578992 C

2. 289461 C

3. 192974 C

4. 96487 C

Subtopic:  Faraday’s Law of Electrolysis |
 68%
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What is the potential of hydrogen electrode in contact with a solution whose pH is 10?

1. 0.591 V

2. -0.591 V

3. 0.295 V

4. -0.295 V

Subtopic:  Nernst Equation |
 71%
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What will be the emf of the cell in which the following reaction takes place? Given Ecell° = 1.05 V

Ni(s)+2Ag+(0.002 M) Ni2+(0.160 M) + 2Ag(s)

1. 0.80 V

2. 0.91 V

3. 0.45 V

4. 0.36 V

Subtopic:  Nernst Equation |
 76%
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The cell in which the following reactions occurs:

2Fe3+(aq)+2I-(aq)2Fe2+(aq)+I2(s) has  \(E_{cell}^{o}\) = 0.236 V at 298 K.

The equilibrium constant of the cell reaction is : 

1. 9.57 × 107
2. 8.43 × 106
3. 3.68 × 10-7
4. 1.74 × 105

Subtopic:  Relation between Emf, G, Kc & pH |
 63%
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The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol−1.

What is the dissociation constant of methanoic acid? Given λ°(H+)= 349.6 S cm2 mol−1 and λ°(HCOO) = 54.6 S cm2 mol-1

1. 2.43 × 104 mol L-1
2. 1.15 × 10-5 mol L-1
3. 3.67 × 10-4 mol L-1
4. 2.44 × 10-6 mol L-1

Subtopic:  Conductance & Conductivity |
 61%
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Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)

EMg2+/Mgo=-2.36 V; ECu2+/Cuo=0.34V

The value of Ecell  for the above reaction is -

1. 3.46 V  2. 3.15 V
3. 2.67 V 4. 1.24 V
Subtopic:  Nernst Equation |
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The cell that will measure the standard electrode potential of a copper electrode is:

1. Pt(s) | H2(g, \(1 \over 10\) bar) | H+(aq, 1M) || Cu2+(aq, 1M) | Cu
2. Pt(s) | H2(g, 1 bar) | H+(aq, 1M) || Cu2+ (aq, 2M) | Cu
3. Pt(s) | H2(g, 1 bar) | H+(aq, 1M)|| Cu2+ (aq, 1M) | Cu
4. Pt(s) | H2(g, \(1 \over 10\) bar) | H+(aq, \(1 \over 10\)M) || Cu2+(aq, 1M) | Cu

Subtopic:  Electrolytic & Electrochemical Cell |
 77%
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The electrode potential for Mg electrode varies according to the equation

\(E_{Mg^{2+}/Mg}\ = \ E_{Mg^{2+}/Mg}^{o} \ - \ \frac{0.059}{2}log\frac{1}{[Mg^{2+}]}\) 

The graph of EMg2+ / Mg vs log [Mg2+] among the following is:

1.    2.  
3.    4.  
Subtopic:  Nernst Equation |
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