$\stackrel{\mathrm{MeOH}}{\to }$A$\stackrel{{\mathrm{PCl}}_3}{\to }$B$\stackrel{{\mathrm{MeNH}}_2}{\to }$C ; Product (C) of the reaction is :

(a)                        (b) 

(c)                              (d) 

$\stackrel{{\mathrm{LiAlH}}_4}{\to }$A$\stackrel{\mathrm{PCC}}{\to }$B$\stackrel{{\mathrm{NH}}_2-{\mathrm{NH}}_2}{\to }$C , Product (C) is :

(a)   (b)        (c)      (d) 

$\stackrel{-{\mathrm{CO}}_2}{\to }$A$\stackrel{\mathrm{HCl}}{\to }$B$\stackrel{\mathrm{aq} \mathrm{KOH}}{\to }$C. Product (C) is :

(a)     $$\begin{gathered} O \\ \left|\right| \\ C{H}_3-C{H}_{2}C-H \end{gathered}$$       (b) 

(c)                        (d) 

 +$\mathrm{R}-{\mathrm{CH}}_2-{\mathrm{NH}}_2$$\underset{\mathrm{THF}}{\overset{{\mathrm{K}}_2{\mathrm{CO}}_3}{\to }}$ (A) 

                                                      (71%)

In above reaction identify major product (A) of the reaction:

(a)     (b) 

(c)        (d) 

$\stackrel{\mathrm{KOH}}{\to }$ A  $\stackrel{{\mathrm{H}}_3{\mathrm{O}}^{+}}{\to }$ B  $\stackrel{{\mathrm{PCl}}_5}{\to }$ C  $\stackrel{{\mathrm{LiAlH}}_4}{\to }$  D  $\stackrel{{\mathrm{H}}^{+}/∆}{\to }$(X)

Product (X) is :

(a)    (b)      (c)        (d) 

A key step in the hydrolysis of acetamide in aqueous acid proceeds by nucleophilic addition of :

(1) ${\mathrm{H}}_3{\mathrm{O}}^{+}$ to    $O$
$\left|\right|$
$C{H}_{3}C N{H}_2$                       

(2)  ${\mathrm{H}}_2\mathrm{O}$ to    $+OH$
$\left|\right|$
$C{H}_{3}C N{H}_2$

(3) ${\mathrm{H}}_3{\mathrm{O}}^{+}$ to  $+OH$
$\left|\right|$
$C{H}_{3}CN{H}_2$                        

(4) ${\mathrm{HO}}^{-}$ to $+OH$
$\left|\right|$
$C{H}_{3}CN{H}_2$

All but one of the following compounds react with aniline to give acetanilide. Which one does not?

$\to$ 

   $$\begin{gathered} O \\ \left|\right| \\ \left(a\right) C{H}_{3}C-Cl \end{gathered}$$                        (b) 

(c) $$\begin{gathered} O \\ \mathbf{\left|}\mathbf{\right|} \\ C{H}_{3}C-H \end{gathered}$$                            (d) 

$\underset{{\mathrm{H}}_2\mathrm{O}}{\overset{{\mathrm{LiAlH}}_4\left(\mathrm{excess}\right)}{\to }}$ Product of the reaction is :

1.                               
2. 

3.                 
4. 

 $$\begin{gathered} C{H}_2‐O‐COR \\ | \\ CH‐O‐CO{R}_2 \\ | \\ C{H}_2‐O‐CO{R}_3 \end{gathered}$$+ $3\mathrm{NaOH} \to \left(\mathrm{A}\right)$ + Salt of fatty acid (soap)

Product (A) of the reaction is :

(a) Ethylene glycol                                    (b) Glycerol

(c) Glyceryltrinitrate (explosive)                 (d) Cumene hydrogen peroxide

(A) ; Product (A) of the reaction is :

1.        
2. 

3.                
4.