Phenol is weakly acidic but does not react with NaHCO3 like carboxylic acids hence:-
1. phenol is weaker than carbonic acid
2. phenol is stronger than carbonic acid
3. phenol is stronger than carboxylic acid
4. none of the above
An organic compound C7H8O is neither soluble in NaOH nor gives blue colour with FeCl3, is:
(1) C6H5.CH2OH
(2)
(3) C6H5.OCH3
(4) none of these
The electrophile involved in the above reaction is:
1. Dichloromethyl cation ()
2. Dichlorocarbene (:CCl2)
3. Trichloromethyl anion ()
4. Formyl cation ()
Which of the following reagents may be used to distinguish between phenol and benzoic acid?
1. Aqueous NaOH
2. Tollens reagent
3. Molisch reagent
4. Neutral FeCl3
In the given transformation, which of the following is the most appropriate reagent ?
(1) Zn-Hg/HCl
(2) Na, Liq. NH3
(3) NaBH4
(4) NH2NH2,OH
An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts the fastest and by what mechanism:
1. secondary alcohol by SN2
2. tertiary alcohol by SN2
3. secondary alcohol by SN1
4. tertiary alcohol by SN1
Sodium phenoxide when heated with CO2 under pressure at 125°C yields a product which on acetylation produces C.
The major product C would be :
(1)
(2)
(3)
(4)
A compound with molecular formula C4H10O3 is converted by the action of acetyl chloride to a compound with molar mass 190. The original compound has:
(1) one OH group
(2) two OH groups
(3) three OH groups
(4) no OH group
Phenyl ethyl ether with concentrated hydrobromic acid on boiling yields:-
1. Phenol and ethyl bromide
2. Bromobenzene and ethanol
3. Phenol and ethane
4. Bromobenzene and ethane
The compound that does not react with sodium is-
1. CH3CHOHCH3
2. CH3 —O—CH3
3. CH3COOH
4. C2H5OH