Allyl isocyanide has:
1. 9 σ, and 4π-bonds.
2. 8 σ, and 5π-bonds
3. 9 σ, and 3π-bonds,
4. 8 σ, and 3 π bonds
Which of the following acids has the smallest dissociation constant?
(1) CH3CHFCOOH
(2) FCH2CH2COOH
(3) BrCH2CH2COOH
(4) CH3CHBrCOOH
Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?
1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
2. \(C H_2=\mathrm{CH}_2-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\stackrel{\oplus}{\mathrm{O}}-\mathrm{CH}_3\)
3. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CH}-\mathrm{O}-\mathrm{CH}_3\)
4. \(\mathrm{CH}_2=\mathrm{CH}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}-\stackrel{\oplus}{\mathrm{C}} \mathrm{H}-\mathrm{O}-\mathrm{CH}_3\)
The least stable resonance structure among the following is:
1.
2.
3.
4.
Hyperconjugation involves the overlap of the following orbitals:
1. σ - σ
2. σ - p
3. p - p
4. π - π
The IUPAC name of the compound shown below is:
1. 2-bromo-6-chlorocyclohex-1-ene
2. 6-bromo-6-chlorocyclohexene
3. 3-bromo-1-chlorocyclohex-1-ene
4. 1-bromo-3-chlorocyclohexene
Which of the following structures are superimposable?
(1)
(2)
(3)
(4)
(1) 1 and 2
(2) 2 and 3
(3) 1 and 4
(4) 1 and 3
The production of an optically active compound from a symmetric molecule without resolution in termed as:
(1) Walden inversion
(2) partial racemisation
(3) asymmetric synthesis
(4) partial resolution
Buta-1,3-diene and But-2-yne are:
1. Position isomers
2. Functional isomers
3. Chain isomers
4. Tautomers
The number of different substitution products possible when ethane is allowed to react with Chlorine in sunlight are:
(1) 9
(2) 6
(3) 8
(4) 5