If the E°cell for a given reaction has a negative value, which of the following gives correct relationships for the values of G° and Keq ?
(1) G° >0; Keq< 1
(2) G° >0; Keq>1
(3) G° < 0; Keq> 1
(4) G° <0; Keq< 1
The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in 60 seconds is (charge on electron = 1.60 x 10-19 C)
1. 6 x 1023
2. 6 x 1020
3. 3.75 x 1020
4. 7.48 x 1023
During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is
(1) 55 minutes
(2) 110 minutes
(3) 220 minutes
(4) 330 minutes
The molar conductivity of a solution of AgNO3 (considering the given data for this solution) at 298 K is:
(a) Concentration: 0.5 mol/dm3
(b) Electrolytic conductivity: 5.76×10–3 S cm–1
1. | 2.88 S cm2/mol | 2. | 11.52 S cm2/mol |
3. | 0.086 S cm2/mol | 4. | 28.8 S cm2/mol |
In the electrochemical cell:
Zn|ZnSO4(0.01 M) || CuSO4(1.0M),Cu, the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that of CuSO4 is changed to 0.01 M, the emf changes to E2. The relationship between E1 and E2 is :
( Given, = 0.059)
1. E1 = E2
2. E1 < E2
3. E1 > E2
4. E2 = 0 E1
The molar conductivity of a 0.5 mol/dm3 solution of AgNO3 with electrolytic conductivity of 5.76 × 10–3 S cm–1 at 298 K is:
1. 11.5 S cm2/mol
2. 21.5 S cm2/mol
3. 31.5 S cm2/mol
4. 41.5 S cm2/mol
The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in 60 seconds is:
(Charge on electron = 1.60 × 10–19 C)
1.
2.
3.
4.
Consider the change in oxidation state of Bromine corresponding to different emf values as shown in the diagram below:
Then the species undergoing disproportionation is:-
1. | \(\text{BrO}^-_3\) | 2. | \(\text{BrO}^-_4\) |
3. | \(\text{Br}_2\) | 4. | \(\text{HBrO}\) |
The pressure of H2 required to make the potential of H2 - electrode zero in pure water at 298 K is:
1. | 10–12 atm | 2. | 10–10 atm |
3. | 10–4 atm | 4. | 10–14 atm |
A device that converts the energy of combustion of fuels, like hydrogen and methane, directly into electrical energy is known as:
1. | Fuel cell. | 2. | Electrolytic cell. |
3. | Dynamo. | 4. | Ni-Cd cell. |