The correct order of strengths of the carboxylic acids :-
(a) I>II>III
(b) II>III>I
(c) III>II>I
(d) lI>I>IlI
The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is:
1. | The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain |
2. | The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain |
3. | The staggered conformation of ethane is more stable than the eclipsed conformation because staggered conformation has no torsional strain |
4. | The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has torsional strain |
In Duma’s method for estimation of nitrogen, 0.25g of an organic compound gave 40 mL
of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension
at 300 K is 25 mm, the percentage of nitrogen in the compound is
1. 17.36
2. 18.20..
3. 16.76
4. 15.76
The compound that gives the most stable carbonium ion after C- Cl bond ionisation among the following is-
1. | 2. | ||
3. | 4. |
consider the following compounds
hyperconjugation occurs in
1. I only
2. II only
3. III only
4. I and III
Which of the following is the most correct electron displacement for a nucleophilic reaction to take place?
The enolic form of ethyl acetoacetate is given below. The number of sigma and pi bonds in the enolic form of ethyl acetoacetate are -
1. 18 sigma bonds and 2 pi-bonds
2. 16 sigma bonds and 1 pi-bond
3. 9 sigma bonds and 2 pi-bonds
4. 9 sigma bonds and 1 pi-bond
Given,
Which of the given compounds can exhibit tautomerism?
1. I and II
2. I and III
3. II and III
4. I, II and III
Which of the following is not correct for a nucleophile?
1. Nucleophile is a Lewis acid
2. Ammonia is a nucleophile
3. Nucleophiles attack low electron density sites
4. Nucleophiles are not electron seeking
In the Kjeldahl's method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralised 10 mL of 1 M H2SO4. The percentage of nitrogen in the soil is
1. 37.33 2. 45.33
3. 35.33 4. 43.33