Be2+ is isoelectronic with which of the following ions?
1. H+
2. Li+
3. Na+
4. Mg2+
A pair among the following that have the same size is:
1. Fe2+, Ni2+
2. Zr4+, Ti4+
3. Zr4+ , Hf4+
4. Zn2+, Hf4+
The correct order of the decreasing ionic radii among the following isoelectronic species is :
1. Ca2+ > K+ > S2- > Cl-
2. Cl- > S2- > Ca2+ > K+
3. S2- > Cl- > K+ > Ca2+
4. K+ > Ca2+ > Cl- > S2-
Which one of the following compounds is a peroxide ?
1. KO2
2. BaO2
3. MnO2
4. NO2
The sequence of ionic mobility in aqueous solution is
1. K+>Na+>Rb+>Cs+
2. Cs+>Rb+>K+>Na+
3. Rb+>K+>Cs+>Na+
4. Na+>K+>Rb+>Cs+
Identify the correct order of the size of the following:
(1) Ca2+<K+<Ar<S2-<Cl-
(2) Ca2+<K+<Ar<Cl-<S2-
(3) Ar<Ca2+<K+<Cl-<S2-
(4) Ca2+<Ar<K+<Cl-<S2-
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:
(1) in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
(2) in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions
(3) in NH3 as well as NF3 the atomic dipole and bond dipole are in opposite directions
(4) in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these are in the same directions
Magnesium reacts with an element (X) to form an ionic compound. If the ground state electronic configuration of (X) is , the simplest formula for this compound is:
1.
2.
3.
4.
1. | B < C < N < O (increasing first ionisation enthalpy) |
2. | I < Br < F < Cl (increasing negative electron gain enthalpy) |
3. | Li < Na < K < Rb (increasing metallic radius) |
4. | Al3+ < Mg2+ < Na+ <F– (increasing ionic size) |
The formation of the oxide ion O2– (g), from the oxygen atom requires first an exothermic and then an endothermic step as shown below,
Thus, the process of formation of O2– in the gas phase is unfavorable even though O2– is isoelectronic with neon. It is due to the fact that:
1. | Electron repulsion outweighs the stability gained by achieving noble gas configuration. |
2. | O– ion has a comparatively smaller size than the oxygen atom. |
3. | Oxygen is more electronegative. |
4. | Addition of electrons in oxygen results in a large size of the ion. |